D-Mannaric acid, di-gamma-lactone

Base Information

• Chemical Name: D-Mannaric acid, di-gamma-lactone
• CAS No.: 2900-01-8
• Molecular Formula: C6H6O6
• Molecular Weight: 174.1082
• DSSTox Substance ID: DTXSID201036535
• Nikkaji Number: J20.361K
• Mol file: 2900-01-8.mol

Synonyms:2900-01-8;D-Mannaric acid, di-gamma-lactone;DTXSID201036535

Chemical Property of D-Mannaric acid, di-gamma-lactone

Chemical Property:

• Vapor Pressure: 8.33E-15mmHg at 25°C
• Boiling Point: 558.6°Cat760mmHg
• Flash Point: 244.5°C
• Density: 1.892g/cm³
• XLogP3: -1.6
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 174.01643791
• Heavy Atom Count: 12
• Complexity: 222

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C12C(C(C(=O)O1)O)OC(=O)C2O
• Isomeric SMILES: [C@@H]12[C@@H]([C@@H](C(=O)O1)O)OC(=O)[C@H]2O

Technology Process of D-Mannaric acid, di-gamma-lactone

There total 11 articles about D-Mannaric acid, di-gamma-lactone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

L-mannono-1,4-lactone (22430-23-5) → mannaric acid-1=>4;6=>3-dilactone (826-91-5,2900-01-8,18404-59-6,18404-63-2,89772-72-5)

Guidance literature:

With nitric acid; at 50 ℃; γ.γ dilactone of/the/ l-manno-sugaroic acid;

Reference yield:

D-mannaric acid (22076-54-6,7231-46-1) → D-mannaro-1,4:6,3-dilactone (2900-01-8)

Guidance literature:

at 20 ℃; for 24h;

DOI:10.1016/j.carres.2013.05.004

Reference yield:

→ D-mannaro-1,4:6,3-dilactone (2900-01-8)

Guidance literature:

With water; bromine; barium benzoate; Unter Lichtausschluss und Behandeln des erhaltenen Barium-Salzes mit wss. Schwefelsaeure und Einengen der Reaktionsloesung;

DOI:10.1021/ja01368a066

upstream raw materials:

D-Mannose

mannitol

mannonic acid

(2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol

Downstream raw materials:

2-furanoic acid

2,5-di-O-benzyl-D-mannaro-1,4:3,6-di-γ-lactone

D-mannaric acid

L-mannitol