trihydro(triethylamine)aluminium

Base Information

• Chemical Name: trihydro(triethylamine)aluminium
• CAS No.: 12076-08-3
• Molecular Formula: C6H18 Al N
• Molecular Weight: 131.197
• Mol file: 12076-08-3.mol

Synonyms:Aluminum,trihydro(triethylamine)- (6CI,7CI,8CI); Alane compound with triethylamine(1:1); Aluminum hydride (AlH3), compd. with N,N-diethylethanamine (1:1);Aluminum hydride(AlH3) compound with triethylamine (1:1); Aluminum trihydridetriethylamine adduct; Ethanamine, N,N-diethyl-, compd. with aluminum hydride(AlH3) (1:1); Triethylamine compound with aluminum hydride (AlH3) (1:1);Triethylamine, compd. with aluminum hydride (AlH3) (1:1); Triethylaminoaluminumhydride

Chemical Property of trihydro(triethylamine)aluminium

Chemical Property:

• Vapor Pressure: 56.1mmHg at 25°C
• Boiling Point: 90.5°Cat760mmHg
• Flash Point: °C
• PSA: 3.24000
• Density: g/cm³
• LogP: 1.68560

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trihydro(triethylamine)aluminium

There total 4 articles about trihydro(triethylamine)aluminium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

lithium aluminium tetrahydride (16853-85-3) + triethylamine hydrochloride (554-68-7) → [AlH3(triethylamine)] (12076-08-3,859039-57-9)

Guidance literature:

In pentane; at 25 ℃;

DOI:10.1021/acs.inorgchem.1c02207

Reference yield: 84.0%

aluminum (III) chloride (7446-70-0,7784-13-6) + lithium aluminium tetrahydride (16853-85-3) + triethylamine (121-44-8) → [AlH3(triethylamine)] (12076-08-3,859039-57-9)

Guidance literature:

In pentane; at -40 - 20 ℃; Schlenk technique; Cooling with ice; Inert atmosphere;

DOI:10.1039/c3dt00046j

Reference yield:

Yb(2+)*Al(3+)*3H(1-)*2C5H3(C(CH3)3)2(1-)*N(C2H5)3=Yb(C5H3(C(CH3)3)2)2AlH3*N(C2H5)3 → [C5H3(C(CH3)3)2]Yb + [AlH3(triethylamine)] (12076-08-3,859039-57-9)

Guidance literature:

In neat (no solvent); Ar-atmosphere; trapping Al-complex (-78°C, 5*10**-3 Torr), heating (80°C, 1 h); elem. anal.;

DOI:10.1016/S0022-328X(96)06678-8

upstream raw materials:

lithium aluminium tetrahydride

triethylamine hydrochloride

aluminum (III) chloride

triethylamine

Downstream raw materials:

aluminium

Refernces

• 1、 Carpentier, Ambre,Maron, Laurent,Morris, Louis J.,Okuda, Jun. "Reductive elimination of [AlH2]+from a cationic Ga-Al dihydride". supporting information. p. 9454 - 9457. Retrieved 2021/09/22.
• 2、 Kickelbick, Guido,Klein, Thomas. "Aluminum nanoparticle preparation: Via catalytic decomposition of alane adducts-influence of reaction parameters on nanoparticle size, morphology and reactivity". supporting information. p. 9820 - 9834. Retrieved 2020/07/30.