DIBENZO(F H)QUINOLINE

Base Information

• Chemical Name: DIBENZO(F H)QUINOLINE
• CAS No.: 217-65-2
• Molecular Formula: C₁₇H₁₁N
• Molecular Weight: 229.281
• Hs Code.: 2933990090
• Mol file: 217-65-2.mol

Synonyms:Phenanthrene-9,10-dicarboximide;dibenzo[e,g]isoindole-1,3-dione;Dibenzochinolin;Phenanthren-9,10-dicarboxy-imid;1-Aza-triphenylene;Phenanthren-9,10-dicarbonsaeure-imid;dibenzo[h,f]quinoline;1H-Dibenz[e,g]isoindole-1,3(2H)-dione;

Chemical Property of DIBENZO(F H)QUINOLINE

Chemical Property:

• Melting Point: 184.0-185.9°C (lit.)
• PSA: 12.89000
• LogP: 4.54120

Purity/Quality:

99% ^*data from raw suppliers

Dibenzo[f,h]quinoline ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DIBENZO(F H)QUINOLINE

There total 8 articles about DIBENZO(F H)QUINOLINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

2,3-dibromopyridine (13534-89-9) + 5,5-dimethyl-5H-dibenzo[b,d]stannole (5565-85-5) → dibenzo[f,h]quinoline (217-65-2)

Guidance literature:

With bis(tri-t-butylphosphine)palladium⁽⁰⁾; In tetrahydrofuran; at 60 ℃; for 12h;

DOI:10.1002/anie.200903779

Reference yield: 70.0%

2-chloronicotinic acid (2942-59-8) + [1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate (189999-35-7) → dibenzo[f,h]quinoline (217-65-2)

Guidance literature:

With potassium carbonate; palladium dichloride; In 1-methyl-pyrrolidin-2-one; at 145 ℃; for 12h; Reagent/catalyst; Solvent; Temperature;

DOI:10.1039/c8cc00300a

Reference yield: 61.0%

di-tert-butyl 1-cyclopropyl-2-(phenanthren-9-yl)hydrazine-1,2-dicarboxylate → dibenzo[f,h]quinoline (217-65-2)

Guidance literature:

With phosphoric acid; In water; 1,2-dichloro-benzene; at 170 ℃; for 24h; under 760.051 Torr;

DOI:10.1002/ange.202005798

upstream raw materials:

9-Aminophenanthrene

glycerol

sulfuric acid

nitrobenzene

Downstream raw materials:

C₅₃H₄₁ClIrNP₂