Plumbane, trimethyl(phenylseleno)-

Base Information

Chemical Name:Plumbane, trimethyl(phenylseleno)-
CAS No.:66166-06-1
Molecular Formula:C9H14PbSe
Molecular Weight:408.37
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Plumbane, trimethyl(phenylseleno)-

Chemical Property:

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Technology Process of Plumbane, trimethyl(phenylseleno)-

There total 2 articles about Plumbane, trimethyl(phenylseleno)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1666-13-3
diphenyl diselenide

: 1520-78-1
trimethyllead chloride

: 66166-06-1
phenylselenotrimethylplumbane

Guidance literature:: With liquid NH₃; Li; In tetrahydrofuran; 100 mL liquid NH3 added to diselenide, to this stirred soln. lithium added until soln. was slightly blue, solvent evaporated under Ar, remaining NH3 removed under vacuum, THF added, solid Me3PbCl in THF added at room temp. under Ar, stirred for 3 h; THF removed at normal pressure, product distilled from react. flask, redistilled, ice water added, organic layer separated, aqueous phase treated with ether, washed, dried, solvent removed, product purified by column chromy.;
DOI:10.1002/(SICI)1099-0682(200006)2000:6<1307::AID-EJIC1307>3.3.CO;2-Q

Reference yield:

: 66166-06-1
phenylselenotrimethylplumbane

Guidance literature:: (CH3)3PbCl, Selen, Phenylgrignard;

Reference yield: 71.0%

: 13709-36-9
xenon difluoride

: 1942-45-6
4-Octyne

: 66166-06-1
phenylselenotrimethylplumbane

: 129053-33-4
(E)-4-fluoro-5-(phenylseleno)oct-4-ene

: 420-54-2
trimethyl lead ⁽¹⁺⁾; fluoride

Guidance literature:: In dichloromethane; XeF2 added in small portions under Ar to a soln. of selenide in CH2Cl2 at -20°C, stirred for 30 min, the acetylene added, stirred for 1 h at -20°C and for 1 h at room temp.; precipitate separated, washed with n-pentane, solvent removed under vacuum, crude product purified by column chromy., elem. anal.;
DOI:10.1002/(SICI)1099-0682(200006)2000:6<1307::AID-EJIC1307>3.3.CO;2-Q