Cyclohepta(6)pyran-5,8-imin-4(5H)-one, 2,3,6,7,8,9-hexahydro-10-methyl-2-phenyl-,(2alpha,5beta,8beta)-(+)-

Base Information

Chemical Name:Cyclohepta(6)pyran-5,8-imin-4(5H)-one, 2,3,6,7,8,9-hexahydro-10-methyl-2-phenyl-,(2alpha,5beta,8beta)-(+)-
CAS No.:75656-91-6
Molecular Formula:C₁₇H₁₉NO₂
Molecular Weight:269.343
Hs Code.:
DSSTox Substance ID:DTXSID20997100
Wikidata:Q27108347
Metabolomics Workbench ID:69593

Synonyms:Strobamine;75656-91-6;C10867;Cyclohepta(6)pyran-5,8-imin-4(5H)-one, 2,3,6,7,8,9-hexahydro-10-methyl-2-phenyl-,(2alpha,5beta,8beta)-(+)-;AC1L9DUT;CHEBI:9291;DTXSID20997100;AKOS040734401;Q27108347;(5S)-12-methyl-5-phenyl-6-oxa-12-azatricyclo[7.2.1.0?,?]dodec-2(7)-en-3-one;(5S)-12-methyl-5-phenyl-6-oxa-12-azatricyclo[7.2.1.02,7]dodec-2(7)-en-3-one;10-Methyl-2-phenyl-2,3,6,7,8,9-hexahydro-5,8-epiminocyclohepta[b]pyran-4(5H)-one

Suppliers and Price of Cyclohepta(6)pyran-5,8-imin-4(5H)-one, 2,3,6,7,8,9-hexahydro-10-methyl-2-phenyl-,(2alpha,5beta,8beta)-(+)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 6 raw suppliers

Chemical Property of Cyclohepta(6)pyran-5,8-imin-4(5H)-one, 2,3,6,7,8,9-hexahydro-10-methyl-2-phenyl-,(2alpha,5beta,8beta)-(+)-

Chemical Property:

Vapor Pressure:2.16E-07mmHg at 25°C
Boiling Point:423.9°Cat760mmHg
Flash Point:210.2°C
Density:1.23g/cm³
XLogP3:2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:269.141578849
Heavy Atom Count:20
Complexity:450

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CN1C2CCC1C3=C(C2)OC(CC3=O)C4=CC=CC=C4
Isomeric SMILES:CN1C2CCC1C3=C(C2)O[C@@H](CC3=O)C4=CC=CC=C4

Technology Process of Cyclohepta(6)pyran-5,8-imin-4(5H)-one, 2,3,6,7,8,9-hexahydro-10-methyl-2-phenyl-,(2alpha,5beta,8beta)-(+)-

There total 2 articles about Cyclohepta(6)pyran-5,8-imin-4(5H)-one, 2,3,6,7,8,9-hexahydro-10-methyl-2-phenyl-,(2alpha,5beta,8beta)-(+)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75638-72-1
(-)-chalcostrobamine

: 75656-91-6
(+)-strobamine

: 1253185-77-1
(-)-epi-strobamine

Guidance literature:: With sulfuric acid; In water; at 50 ℃; for 24h;
DOI:10.3998/ark.5550190.0011.409

Reference yield:

: 532-24-1
tropinone

: 60299-77-6
cinnamoyl cyanide

: 75656-91-6
(+)-strobamine

: 1253185-77-1
(-)-epi-strobamine

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium; hydrochloride salt of (1S,1'S)-bis(1-phenylethyl)amine / tetrahydrofuran / 3 h / -78 °C

1.2: 1 h / -78 °C

2.1: sulfuric acid / water / 24 h / 50 °C

With n-butyllithium; sulfuric acid; hydrochloride salt of (1S,1'S)-bis(1-phenylethyl)amine; In tetrahydrofuran; water;
DOI:10.3998/ark.5550190.0011.409