Europium bromide

Base Information

• Chemical Name: Europium bromide
• CAS No.: 13759-88-1
• Molecular Formula: Br3Eu
• Molecular Weight: 391.672
• Hs Code.: 2846902010
• DSSTox Substance ID: DTXSID9065609
• Wikidata: Q15628204
• Mol file: 13759-88-1.mol

Synonyms:tribromoeuropium;Europium bromide;EUROPIUM (III) BROMIDE;UNII-TQ32498BDX;DTXSID9065609;EINECS 237-349-5;Q15628204

Chemical Property of Europium bromide

Chemical Property:

• Melting Point: 702°C
• Boiling Point: decomposes [CRC10]
• PSA: 0.00000
• LogP: 2.53680
• Sensitive.: Hygroscopic
• Water Solubility.: soluble H2O [CRC10]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 391.67420
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

99% ^*data from raw suppliers

Europium bromide hydrate, 99.99% (REO) 99.99% (REO) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: Br[Eu](Br)Br

Technology Process of Europium bromide

There total 5 articles about Europium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

europium(III) bromide hexahydrate → europium(III) bromide (13759-88-1)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Eu compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield:

europium(III) oxide + aluminium bromide (7727-15-3) → aluminum oxide (1333-84-2,1344-28-1) + europium(III) bromide (13759-88-1)

Guidance literature:

With aluminium; In solid; Ln2O3, AlBr3 (Ln:Al = 1:4) and Al powder were placed into an one-end sealed quartz tube under Ar, sealed under vac., heated at 600 K for 1 h; sealed tube was placed in a tubular furnace with a reduced temp. gradient from 750 to 460 K, vapor transport reaction for 6 h, tube was quicklyremoved from the furnace, the hot end was quenched with water, AlBr3 wa s condensed;

DOI:10.1021/ic061795z

Reference yield:

europium(III) oxide + bromine (7726-95-6) → europium(III) bromide (13759-88-1)

Guidance literature:

With aluminium; In solid; liquid Br2 was dropped into a solid mixt. of oxide and a large excess ofAl powder in one-end sealed quartz tube under Ar atm., evacuated, seale d, placed in a tabular furnace with temp. gradient from 750 to 460 K;

DOI:10.1021/ic061795z

upstream raw materials:

hydrogen bromide

bromine

aluminium bromide

Downstream raw materials:

[Eu(C₁₈H₁₇N₃O₂)2Br₂]⁽¹⁺⁾*Br^(1-) = [Eu(C₁₈H₁₇N₃O₂)2Br₂]Br

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