Bromhydrol

Base Information

• Chemical Name: Bromhydrol
• CAS No.: 7727-15-3
• Deprecated CAS: 39380-76-2,56803-00-0
• Molecular Formula: AlBr3
• Molecular Weight: 266.694
• Hs Code.: 28275900
• UNII: IY20HBK5LK
• DSSTox Substance ID: DTXSID2064783
• Nikkaji Number: J3.107K
• Mol file: 7727-15-3.mol

Synonyms:Bromhydrol;Al bromohydrate;Basic aluminum bromide;Aluminum hydroxybromide;Aluminum bromide, basic;aluminum tri-bromide;aluminum(III) bromide;ALUMINUM BROMIDE [MI];ALUMINUM BROMIDE [HSDB];DTXSID2064783;AKOS024438101;AKOS032950058;12794-92-2;LS-16460;Aluminum bromide, 99.99% trace metals grade

Chemical Property of Bromhydrol

Chemical Property:

• Appearance/Colour: white crystalline powder
• Melting Point: 94-98 °C(lit.)
• Boiling Point: 265 °C
• Flash Point: 268°C subl.
• PSA: 0.00000
• Density: 3.205 g/mL at 25 °C(lit.)
• LogP: 2.53680
• Water Solubility.: decomposes
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 265.73450
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): C,Xi,N,F
• Hazard Codes: C:Corrosive
• Statements: R22:; R34:
• Safety Statements: S36/37/39:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Al+3].[Br-].[Br-].[Br-]

Technology Process of Bromhydrol

There total 26 articles about Bromhydrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

phenylaluminium dichloride (3530-39-0) + allyl bromide (106-95-6) → allylbenzene (300-57-2,57807-91-7) + biphenyl (92-52-4,1594-86-1) + aluminium bromide (7727-15-3)

Guidance literature:

bis(η3-allyl-μ-chloropalladium(II)); In diethyl ether; Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 8 h);

DOI:10.1007/BF00959210

Reference yield: 37.0%

diphenylaluminum chloride (6591-30-6) + allyl bromide (106-95-6) → allylbenzene (300-57-2,57807-91-7) + biphenyl (92-52-4,1594-86-1) + aluminium bromide (7727-15-3)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In diethyl ether; Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 20 h);

DOI:10.1007/BF00959210

Reference yield:

AsBr4(1+)*AlBr4(1-)={AsBr4}{AlBr4} (119484-32-1) → bromine (7726-95-6) + aluminium bromide (7727-15-3) + arsenic(III) bromide (7784-33-0)

Guidance literature:

equilibrium at room temp.;

DOI:10.1039/C39880001426

upstream raw materials:

1,1-dibromomethane

Bromoform

aluminum oxide

disulphur dibromide

Downstream raw materials:

ethyl bromide

chloroethane

n-heptan1ol

4,5,6,7-tetrabromo-benzo[1,3]dioxole

Refernces

• 1、 Rusin,Nisel'Son. "Complex equilibria in unsaturated vapor over AlBr3". . p. 1801 - 1807. Retrieved 2008.
• 2、 Willems, Johannes B.,Rohm, Henning W.,Geers, Christine,Koeckerling, Martin. "Reversible bromide-chloride exchange in zirconium cluster compounds: Synthesis by means of ionic liquids, structures, and some spectral data of (EMIm)4[(Zr6Z)Br18] cluster phases (Z = Be, Fe)". . p. 6197 - 6203. Retrieved 2007.