Lead(II) thiocyanate

Base Information

• Chemical Name: Lead(II) thiocyanate
• CAS No.: 592-87-0
• Deprecated CAS: 10382-36-2,14287-09-3,953087-97-3
• Molecular Formula: CHNS . 1/2Pb
• Molecular Weight: 439.535
• Hs Code.: 29309099
• European Community (EC) Number: 209-774-6
• UN Number: 2291
• UNII: 7977FZ765Q
• DSSTox Substance ID: DTXSID90890513
• Nikkaji Number: J43.849I
• Wikipedia: Lead(II) thiocyanate,Lead(II)_thiocyanate
• Mol file: 592-87-0.mol

Synonyms:lead(II) thiocyanate

Chemical Property of Lead(II) thiocyanate

Chemical Property:

• Appearance/Colour: White to yellow powder
• Melting Point: 190 °C (dec.)(lit.)
• Boiling Point: 146 °C at 760 mmHg
• Flash Point: 42.1 °C
• PSA: 98.18000
• Density: 3.82 g/mL at 25 °C(lit.)
• LogP: 0.94916
• Solubility.: cold water: soluble200 part(lit.)
• Water Solubility.: soluble ~200 parts cold, 50 parts boiling H2O [MER06]; g/L H2O: 0.0137 (18°) [KRU93]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 323.92694
• Heavy Atom Count: 7
• Complexity: 31.3
• Transport DOT Label: Poison

Purity/Quality:

99% ^*data from raw suppliers

Lead(II) thiocyanate 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T, N
• Hazard Codes: T,N
• Statements: 61-20/21/22-32-33-50/53-62
• Safety Statements: 53-13-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Lead Compounds, Inorganic
• Canonical SMILES: C(#N)[S-].C(#N)[S-].[Pb+2]
• Description: It has many applications such as phosphorus-free matches, dyeing, and explosives, especially an ingredient in primes for cartridges. Moreover, this chemical can also act as an effective agent for enhancing the performance of perovskite solar cells. For example, planar perovskite solar cells exhibit a reduced hysteresis and boosted fill factor after introducing lead thiocyanate additive.1 Using this additive, the improved performance is further verified in the formamidinium and cesium lead triiodide perovskite solar cells.2 In addition, antigen retrieval can be realized by microwave irradiation in lead thiocyanate.3 Besides, an efficient stereoselective 1,2-dithiocyanation of various alkynes has been accomplished by employing this chemical as a reagent.4
• Uses: Reverse dyeing with aniline black; manufacture of safety matches and cartridges. Lead (II) thiocyanate can be used:To form a complex with Schiff-base lariat crown ether,?N,N′-bis(3-(salicylaldimino)benzyl)-4,13-diaza-18-crown-6.To investigate complexing and fluorescence properties of calixarene bearing two dansyl fluorophores grafted on a large pore mesoporous silica material.As a reagent in the 1,2-dithiocyanation of alkynes in the presence of (dichloroiodo)benzene.As a precursor to synthesize perovskite films for solar cell applications.

Technology Process of Lead(II) thiocyanate

There total 26 articles about Lead(II) thiocyanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

ammonium thiocyanate + lead(II) nitrate → lead(II) thiocyanate (592-87-0)

Guidance literature:

In water; addn. of 1M aq. Pb(NO3)2 soln. to 136ml 10M NH4SCN soln. at 5°C, stirring for 30min; (exclusion of light);; washing with H2O of 5°C, drying in vac. over P2O5 for about 8d; (exclusion of light);;

Reference yield:

lead(II) nitrate + potassium thioacyanate (333-20-0) → lead(II) thiocyanate (592-87-0)

Guidance literature:

In water; addn. of 90g KSCN in 840ml H2O to 150g Pb(NO3)2 in 1500ml H2O at ambient temp. while stirring, cooling, crystn.;; filtration in the cold, washing with ice-cooled H2O, drying on clay in the dark; yield: 90g;;

Reference yield:

lead(II) nitrate + ammonium thiocyanate (1147550-11-5) → lead(II) thiocyanate (592-87-0)

Guidance literature:

In water;

DOI:10.14233/ajchem.2018.21472

upstream raw materials:

potassium thioacyanate

lead(IV) tetraacetate

sodium thiocyanide

lead⁽²⁺⁾ cation

Downstream raw materials:

5-methyl-2-o-toluidino-thiazol-4-one

4-dimethylamino-benzoyl isothiocyanate

2-furoylisothiocyanate

trimethylsilyl isothiocyanate

Refernces

Thermal decomposition of Bi(III), Cd(II), Pb(II) and Cu(II) thiocyanates

10.1023/A:1011501307497

The search investigates the thermal decomposition processes of Bismuth(III) Thiocyanate (Bi(SCN)3), Cadmium(II) Thiocyanate (Cd(SCN)2), Lead(II) Thiocyanate (Pb(SCN)2), and Copper(II) Thiocyanate (Cu(SCN)2). The study employs thermal analysis curves, X-ray diffraction, and chemical analysis to determine the nature of the reactions and the gaseous products (SO2 and CO2) released during decomposition. The compounds were heated in an electric furnace in an air atmosphere, and the decomposition stages were identified through TG, DTG, and DTA curves. The results show that each compound decomposes in multiple stages, with distinct intermediate and final products. For instance, Bi(SCN)3 decomposes into Bi2O3 and (BiO)2SO4, while Cd(SCN)2 forms CdO, Pb(SCN)2 yields PbO, and Cu(SCN)2 ultimately produces CuO. The study provides detailed insights into the thermal decomposition mechanisms of these metal thiocyanates, which are significant for analytical methods involving thiocyanates and for understanding the thermal behavior of related compounds.