Methyl 2,6-dimethyl-4-oxocyclohex-2-enecarboxylate

Base Information

Chemical Name:Methyl 2,6-dimethyl-4-oxocyclohex-2-enecarboxylate
CAS No.:67333-67-9
Molecular Formula:C10H14O3
Molecular Weight:182.219
Hs Code.:
DSSTox Substance ID:DTXSID00456548
Nikkaji Number:J502.608C

Synonyms:Methyl 2,6-dimethyl-4-oxocyclohex-2-enecarboxylate;67333-67-9;2-Cyclohexene-1-carboxylic acid, 2,6-dimethyl-4-oxo-, methyl ester;METHYL 2,6-DIMETHYL-4-OXOCYCLOHEX-2-ENE-1-CARBOXYLATE;SCHEMBL11489215;DTXSID00456548;MFCD22571578;DS-19389;CS-0161504;D97497;Methyl2,6-dimethyl-4-oxocyclohex-2-enecarboxylate;1,5-Dimethyl-3-oxocyclohexene-6-carboxylic acid methyl ester

Suppliers and Price of Methyl 2,6-dimethyl-4-oxocyclohex-2-enecarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 9 raw suppliers

Chemical Property of Methyl 2,6-dimethyl-4-oxocyclohex-2-enecarboxylate

Chemical Property:

XLogP3:0.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:182.094294304
Heavy Atom Count:13
Complexity:265

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1CC(=O)C=C(C1C(=O)OC)C

Technology Process of Methyl 2,6-dimethyl-4-oxocyclohex-2-enecarboxylate

There total 4 articles about Methyl 2,6-dimethyl-4-oxocyclohex-2-enecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 75-07-0,9002-91-9
acetaldehyde

: 141-78-6
ethyl acetate

: 67333-67-9
methyl 2,6-dimethyl-4-oxo-2-cyclohexene-1-carboxylate

Guidance literature:: With piperidine; In ethanol; at -5 - 100 ℃; Inert atmosphere;
DOI:10.3998/ark.5550190.0011.410

Reference yield:

: 75-07-0,9002-91-9
acetaldehyde

: 105-45-3
acetoacetic acid methyl ester

: 67333-67-9
methyl 2,6-dimethyl-4-oxo-2-cyclohexene-1-carboxylate

Guidance literature:: With piperidine; In methanol; at 20 ℃; for 48h;
DOI:10.5012/bkcs.2011.32.5.1725

Reference yield:

: 105-45-3
acetoacetic acid methyl ester

: 123269-14-7
Diethyl (E)-2-oxo-3-pentenylphosphonate

: 67333-67-9
methyl 2,6-dimethyl-4-oxo-2-cyclohexene-1-carboxylate

Guidance literature:: With sodium hydride; Yield given. Multistep reaction; 1.) THF, RT, 30 min, 2.) THF, 0 deg C, 2 h;
DOI:10.1246/bcsj.65.2456