Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester

Base Information

Chemical Name:Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester
CAS No.:10138-32-6
Molecular Formula:C10H14O2
Molecular Weight:166.22
Hs Code.:2916209090
NSC Number:62714,26489
DSSTox Substance ID:DTXSID30884451
Nikkaji Number:J41.837D
Mol file:10138-32-6.mol

Synonyms:10138-32-6;ETHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE;Ethyl 5-norbornene-2-carboxylate;Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester;5-Norbornene-2-carboxylic acid, ethyl ester;NSC 26489;UNII-QEA96R4A1Z;2,5-Endomethylene-3-cyclohexene carboxylic acid, ethyl ester;BICYCLO(2.2.1)HEPT-5-ENE-2-CARBOXYLIC ACID, ETHYL ESTER;WLN: L55 A CUTJ FVO2;ethyl bicyclo[2.2.1]hept-2-ene-5-carboxylate;NSC26489;NCIOpen2_000131;QEA96R4A1Z;2-ethoxycarbonyl-5-norbornene;SCHEMBL200507;DTXSID30884451;NSC62714;NSC-26489;NSC-62714;AKOS015917768;AC-4862;AS-75467;LS-43706;FT-0766049;Norborna-2-ene-5-carboxylic acid ethyl ester;E77868;J-650254;bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester;Ethyl (1S,2S,4S)-bicyclo[2.2.1]hept-5-ene-2-carboxylate

Suppliers and Price of Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Ethylbicyclo[2.2.1]hept-5-ene-2-carboxylate 97%
10g
$ 60.00

Chemenu
ethylbicyclo[2.2.1]hept-5-ene-2-carboxylate 97%
100g
$ 337.00

American Custom Chemicals Corporation
ETHYL-5-NORBORNENE-2-CARBOXYLATE 95.00%
1G
$ 686.88

Ambeed
Ethylbicyclo[2.2.1]hept-5-ene-2-carboxylate 98%
500g
$ 729.00

Ambeed
Ethylbicyclo[2.2.1]hept-5-ene-2-carboxylate 98%
100g
$ 223.00

Ambeed
Ethylbicyclo[2.2.1]hept-5-ene-2-carboxylate 98%
25g
$ 65.00

Ambeed
Ethylbicyclo[2.2.1]hept-5-ene-2-carboxylate 98%
5g
$ 18.00

Total 36 raw suppliers

Chemical Property of Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester

Chemical Property:

Vapor Pressure:0.142mmHg at 25°C
Refractive Index:1.508
Boiling Point:216.164 °C at 760 mmHg
Flash Point:75.303 °C
PSA：26.30000
Density:1.089 g/cm³
LogP:1.76170
XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:166.099379685
Heavy Atom Count:12
Complexity:220

Purity/Quality:

99%, ^*data from raw suppliers

Ethylbicyclo[2.2.1]hept-5-ene-2-carboxylate 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CCOC(=O)C1CC2CC1C=C2

Technology Process of Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester

There total 18 articles about Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 140-88-5,9003-32-1
ethyl acrylate

: 10138-32-6
bicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid ethyl ester

Guidance literature:: With lithium perchlorate; In diethyl ether; for 5h; Product distribution; Ambient temperature; other dienes and dienophiles; other solvents, temp., and reaction times;
DOI:10.1021/ja00167a096

Reference yield: 83.0%

: 42216-96-6
triethyl orthoacrylate

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 10138-32-6
bicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid ethyl ester

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -78 - -5 ℃; for 3h; Product distribution; Mechanism; other 1,3-dienes, var. conditions;
DOI:10.1021/jo00245a058

Reference yield: 48.0%

: C₁₄H₂₃O₅P

: 95-12-5,13360-81-1,15507-06-9,42070-72-4,67505-46-8,67671-05-0,67671-06-1,69831-10-3,42070-82-6
(-)-(1S,2S,4S)-bicyclo[2.2.1]hept-5-en-2-yl methanol

: 10138-32-6,51789-92-5,51789-95-8,105367-96-2
ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; dichloromethane; at 0 - 20 ℃; for 3h; Cooling with ice; Inert atmosphere;
DOI:10.1055/s-0031-1290485