Triethylammonium diethyldithiocarbamate

Base Information

• Chemical Name: Triethylammonium diethyldithiocarbamate
• CAS No.: 2391-78-8
• Molecular Formula: C11H26N2S2
• Molecular Weight: 250.473
• Hs Code.: 2930909090
• European Community (EC) Number: 219-240-4
• DSSTox Substance ID: DTXSID8062369
• Mol file: 2391-78-8.mol

Synonyms:Triethylammonium diethyldithiocarbamate;2391-78-8;diethylcarbamodithioic acid;N,N-diethylethanamine;EINECS 219-240-4;SCHEMBL4713616;C6H15N.C5H11NS2;DTXSID8062369;AKOS015894263;C6-H15-N.C5-H11-N-S2;Carbamodithioic acid, diethyl-, compound with N,N-diethylethanamine (1:1)

Chemical Property of Triethylammonium diethyldithiocarbamate

Chemical Property:

• Vapor Pressure: 1.1mmHg at 25°C
• Melting Point: 82-84 °C(lit.)
• Boiling Point: 176.4°Cat760mmHg
• Flash Point: 60.5°C
• PSA: 39.77000
• Density: g/cm³
• LogP: 1.09100
• Sensitive.: Hygroscopic
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 250.15374118
• Heavy Atom Count: 15
• Complexity: 104

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCN(CC)CC.CCN(CC)C(=S)S

Technology Process of Triethylammonium diethyldithiocarbamate

There total 1 articles about Triethylammonium diethyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + diethylamine (109-89-7) + triethylamine (121-44-8) → N,N-diethyldithiocarbamate triethylamine salt (2391-78-8)

Guidance literature:

In diethyl ether;

Reference yield: 63.9%

N,N-diethyldithiocarbamate triethylamine salt (2391-78-8) + benzhydryl (6R,7R)-7β-[(phenylacetyl)amino]-3-[(methylsulfonyl)oxy]-3-cephem-4-carboxylate (92096-37-2) → C33H33N3O4S3

Guidance literature:

benzhydryl (6R,7R)-7β-[(phenylacetyl)amino]-3-[(methylsulfonyl)oxy]-3-cephem-4-carboxylate; With sodium carbonate; In dichloromethane; at 0 ℃; for 0.0833333h;

N,N-diethyldithiocarbamate triethylamine salt; In dichloromethane; at 0 ℃; for 6h;

Reference yield: 62.0%

N,N-diethyldithiocarbamate triethylamine salt (2391-78-8) + N,N-diethylthiocarbamoyl chloride (88-11-9) → tetraethylthiuram monosulfide (95-05-6)

Guidance literature:

In acetonitrile; at 20 ℃; for 12h;

DOI:10.1016/j.ejmech.2020.112500

upstream raw materials:

carbon disulfide

diethylamine

triethylamine

Downstream raw materials:

(4R,5S,6S)-3-Diethylthiocarbamoylsulfanyl-6-((R)-1-hydroxy-ethyl)-4-methyl-7-oxo-1-aza-bicyclo[3.2.0]hept-2-ene-2-carboxylic acid 4-nitro-benzyl ester

methyl diethyldithiocarbamate

disulfiram

S-(β-D-glucopyranosyl) N,N-diethyldithiocarbamate

Refernces

• 1、 Xu, Yi-xiang,Huang, Yun-yuan,Song, Rong-rong,Ren, Yan-liang,Chen, Xin,Zhang, Chao,Mao, Fei,Li, Xiao-kang,Zhu, Jin,Ni, Shuai-shuai,Wan, Jian,Li, Jian. "Development of disulfide-derived fructose-1,6-bisphosphatase (FBPase) covalent inhibitors for the treatment of type 2 diabetes". . . Retrieved 2020/07/25.
• 2、 Varun, Begur Vasanthkumar,Prabhu, Kandikere Ramaiah. "A non-isothiocyanate route to synthesize trisubstituted thioureas of arylamines using in situ generated dithiocarbamates". . p. 3079 - 3087. Retrieved 2013/04/24.