Bis(2-nitrophenyl) diselenide

Base Information

• Chemical Name: Bis(2-nitrophenyl) diselenide
• CAS No.: 35350-43-7
• Molecular Formula: C12H8 N2 O4 Se2
• Molecular Weight: 402.127
• Hs Code.: 29310099
• European Community (EC) Number: 252-522-5
• NSC Number: 516220
• DSSTox Substance ID: DTXSID50188842
• Nikkaji Number: J260.595C
• ChEMBL ID: CHEMBL4059960
• Mol file: 35350-43-7.mol

Synonyms:35350-43-7;Bis(2-nitrophenyl) diselenide;bis(2-Nitrophenyl)diselenide;1-nitro-2-[(2-nitrophenyl)diselanyl]benzene;1,2-Bis(2-nitrophenyl)diselane;EINECS 252-522-5;CHEMBL4059960;bis(2-nitrophenyl)diselane;Diselenide, bis(2-nitrophenyl);C12H8N2O4Se2;Bis(2-nitrophenyl) perselenide;diselane, bis(2-nitrophenyl)-;SCHEMBL10387637;DTXSID50188842;1,2-Bis(2-nitrophenyl)diselane #;BDBM50248563;MFCD01632548;NSC516220;BIS-(2-NITROPHENYL)DISELENIDE;AKOS025213591;NSC 516220;NSC-516220;AC-31137;FT-0698307;S11584

Chemical Property of Bis(2-nitrophenyl) diselenide

Chemical Property:

• Vapor Pressure: 6.68E-11mmHg at 25°C
• Melting Point: 212-213 °C
• Boiling Point: 533°Cat760mmHg
• Flash Point: 276.1°C
• PSA: 91.64000
• Density: g/cm³
• LogP: 1.82360
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 403.88145
• Heavy Atom Count: 20
• Complexity: 324

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,2-Bis(2-nitrophenyl)diselane 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: N-T
• Statements: 50/53-33-23/25
• Safety Statements: 61-60-45-28A-20/21

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)[N+](=O)[O-])[Se][Se]C2=CC=CC=C2[N+](=O)[O-]

Technology Process of Bis(2-nitrophenyl) diselenide

There total 36 articles about Bis(2-nitrophenyl) diselenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

2-Chloronitrobenzene (88-73-3) → bis(o-nitrophenyl) diselenide (35350-43-7)

Guidance literature:

With dilithium diselenide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; for 20h; Ambient temperature;

DOI:10.1016/S0040-4020(01)89801-X

Reference yield: 82.0%

2-nitrophenyl bromide (577-19-5) → bis(o-nitrophenyl) diselenide (35350-43-7)

Guidance literature:

With selenium; 1,10-Phenanthroline; caesium carbonate; copper(l) chloride; In 1,4-dioxane; at 110 ℃; for 24h; Inert atmosphere;

Reference yield: 80.0%

o-nitroiodobenzene (609-73-4) → bis(o-nitrophenyl) diselenide (35350-43-7)

Guidance literature:

With selenium; 1,10-Phenanthroline; copper(II) choride dihydrate; tetrabutyl ammonium fluoride; caesium carbonate; In water; at 120 ℃; for 24h; Sealed tube;

DOI:10.1039/c3ob40464a

upstream raw materials:

methanol

ortho-nitrophenyl selenocyanate

sodium methylate

(2-nitro-phenyl)-phenyl diselenide

Downstream raw materials:

2-nitrophenyl propargyl selenide

(2-nitrophenyl)(1-phenyl-3-(trifluoromethyl)naphthalen-2-yl)selane

C₄₁H₄₇N₄O₂Se⁽¹⁺⁾

2-(o-nitrophenylseleno)hydroquinone dimethyl ether

Refernces

• 1、 -. "Naphthalimide derivative containing selenoheterocycle, and preparation method and antiviral application thereof (by machine translation)". Paragraph 0022; 0053. . Retrieved 2020/07/12.
• 2、 -. "Compound for treatment or prevention of breast cancer". Paragraph 0059; 0060; 0063. . Retrieved 2018/02/04.