Lanthanum(III) chloride

Base Information

• Chemical Name: Lanthanum(III) chloride
• CAS No.: 10099-58-8
• Deprecated CAS: 12314-13-5
• Molecular Formula: Cl3La
• Molecular Weight: 245.264
• Hs Code.: 28469023
• European Community (EC) Number: 233-237-5
• UN Number: 1760
• DSSTox Substance ID: DTXSID2051502
• Wikipedia: Lanthanum(III) chloride
• Wikidata: Q421212
• Mol file: 10099-58-8.mol

Synonyms:Lanthanum(III) chloride;10099-58-8;Lanthanum trichloride;trichlorolanthanum;Lanthanum chloride (LaCl3);Lanthanum chloride, anhydrous;Lanthanum chloride (La2Cl6);CCRIS 6887;EINECS 233-237-5;MFCD00011068;Lanthanum(III) chloride, anhydrous;LaCl3;UNII-04M8624OXV;DTXSID2051502;Lanthanum(III) chloride, ultra dry;AKOS032963570;SC10964;LS-87579;Lanthanum(III) chloride, anhydrous, beads;Lanthanum(III) chloride, anhydrous, LaCl3;FT-0689205;FT-0699501;EC 233-237-5;Q421212;Lanthanum(III) chloride, anhydrous (99.9%-La) (REO);Lanthanum(III) chloride, anhydrous, beads, -10 mesh, >=99.99% trace metals basis;Lanthanum(III) chloride, anhydrous, beads, -10 mesh, 99.9% trace metals basis;LANTHANUM CHLORIDE;LANTHANUM TRICHLORIDE;LANTHANUM(III) CHLORIDE;Lanthanum(III) chloride, anhydrous, ?LaCl3

Chemical Property of Lanthanum(III) chloride

Chemical Property:

• Appearance/Colour: white powder or colourless crystals
• Melting Point: 860 °C(lit.)
• Boiling Point: 1812 °C(lit.)
• Flash Point: 1000oC
• PSA: 0.00000
• Density: 3.84 g/mL at 25 °C(lit.)
• LogP: 2.06850
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 243.812921
• Heavy Atom Count: 4
• Complexity: 8
• Transport DOT Label: Corrosive

Purity/Quality:

99% 99.9% 99.99% ^*data from raw suppliers

Lanthanum(III) chloride, anhydrous (99.9%-La) (REO) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi,N
• Statements: 36/37/38-11-51/53-43-41
• Safety Statements: 26-36-61-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Rare Earth Metals
• Canonical SMILES: Cl[La](Cl)Cl
• Physical Properties: The anhydrous chloride is a white hexagonal crystal; hygroscopic; density 3.84 g/cm3; melts at 850°C; soluble in water. The heptahydrate is a white triclinic crystal; decomposes at 91°C; soluble in water and ethanol.
• Uses: Lanthanum(III) chloride is used to prepare other lanthanum salts. The anhydrous chloride is employed to produce lanthanum metal. Lanthanum chloride is used to prepare other lanthanum salts. The anhydrous chloride is employed to produce lanthanum metal. Lanthanum chloride is a precursor for synthesis of lanthanum phosphate nano rods and used in gamma detectors. It is also used as a catalyst for high pressure oxidative chlorination of methane to chloromethane with hydrochloric acid and oxygen. In organic synthesis, lanthanum trichloride acts as lewis acid for the conversion of aldehydes to acetals.

Technology Process of Lanthanum(III) chloride

There total 39 articles about Lanthanum(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

lanthanum tert-butoxycuprate → lanthanum(III) chloride (10099-58-8) + copper(l) chloride

Guidance literature:

With HCl; In tetrahydrofuran; gaseous HCl was condensed into soln. of La complex in THF to result in a formation of finely dispersed ppt.; ppt. of CuCl sepd. by centrifugation, washed with water under Ar, driedin vacuo at 50°; aq. soln. evapd. to dryness to give LaCl3; products identified by elem. anal.;

DOI:10.1007/BF02495773

Reference yield: 99.0%

([La(μ-Cl)(H2O)7](Cl)2)2 → lanthanum(III) chloride (10099-58-8)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating La compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield: 85.0%

hydrogenchloride (7647-01-0,15364-23-5) + lanthanum(III) oxide → lanthanum(III) chloride (10099-58-8)

Guidance literature:

In hydrogenchloride; metal oxide treated with 1:1 hydrochloric acid; soln. filtered, evapd. to dryness, crystals dried in vaccum dessicator over CaCl2;

DOI:10.1081/SIM-120003800

upstream raw materials:

hydrogenchloride

lanthanum(III) chloride hydrated

lanthanum(III) chloride hexahydrate

chlorine

Downstream raw materials:

La⁽³⁺⁾*C₁₄H₁₀N₂OS^(2-)*Cl^(1-)*H₂O=La(C₁₄H₁₀N₂OS)Cl*H₂O

Refernces

• 1、 Mattausch, Hansjuergen,Zheng, Chong,Ryazanov, Mikhail,Simon, Arndt. "Reduced lanthanum halides with Ge as interstitials: La2I 2Ge, La2I2Ge2, La3Cl 2Ge3, La3Br2Ge3, La 3I3Ge, La". . p. 302 - 308. Retrieved 2005.
• 2、 Andrews, Philip C.,Junk, Peter C.,Massi, Massimiliano,Silberstein, Morry. "Gelation of La(III) cations promoted by 5-(2-pyridyl)tetrazolate and water". . p. 3317 - 3319. Retrieved 2006.
• 3、 Van Der Heijden, Alwies W. A. M.,Podkolzin, Simon G.,Jones, Mark E.,Bitter, Johannes H.,Weckhuysen, Bert M.. "Catalytic hydrogen-chlorine exchange between chlorinated hydrocarbons under oxygen-free conditions". . p. 5002 - 5004. Retrieved 2008.
• 4、 Refat, Moamen S.,El-Hawary,Mohamed, Mahmoud A.. "Study of the chemical chelates and anti-microbial effect of some metal ions in nanostructural form on the efficiency of antibiotic therapy norfloxacin drug ". . p. 45 - 54. Retrieved 2012.
• 5、 Xiong, Ding-Bang,Zhao, Yu-Feng,Gulay, Lubomir D.,Zhao, Jing-Tai. "Lanthanum phosphite microspheres: Hydrothermal synthesis, ab initio structure determination, morphology and photoluminescence of La(HO)(HPO 3)". . p. 4522 - 4527. Retrieved 2009.
• 6、 Puntus, Lada,Zhuravlev, Konstantin,Lyssenko, Konstantin,Antipin, Mikhail,Pekareva, Irina. "Luminescence and structural properties of lanthanide complexes of Schiff bases derived from pyridoxal and amino acids". . p. 4079 - 4088. Retrieved 2007.
• 7、 Chen, Hongbing,Yang, Peizhi,Zhou, Changyong,Jiang, Chengyong. "Bridgman growth of LaCl3:Ce3+ crystal in non-vacuum atmosphere". . p. 172 - 175. Retrieved 2008.
• 8、 Ahn, Kyungsoo,Gibson, Brendan J.,Kremer, Reinhard K.,Mattausch, Hansjuergen,Stolovits, Andres,Simon, Arndt. "Layered lanthanum carbide halide superconductors La2C2(X,X′)2 (X,X′ = Cl, Br, I): Neutron powder diffraction characterization and electronic properties". . p. 5446 - 5453. Retrieved 1999.
• 9、 Woodman, Timothy J.,Schormann, Mark,Bochmann, Manfred. "Synthesis, characterization, and reactivity of ansα-Bis(allyl) Lanthanide complexes, a new class of single-component methyl methacrylate polymerization catalysts". . p. 2938 - 2943. Retrieved 2003.
• 10、 Zheng, Chong,Mattausch, Hansjuergen,Hoch, Constantin,Simon, Arndt. "A cluster with a mixed M6X12/M6X8 environment: The La6Cl11Co structure". . p. 2307 - 2311. Retrieved 2009.