3,3'-Diaminobenzophenone

Base Information

• Chemical Name: 3,3'-Diaminobenzophenone
• CAS No.: 611-79-0
• Molecular Formula: C13H12N2O
• Molecular Weight: 212.251
• Hs Code.: 2922399090
• European Community (EC) Number: 210-281-3
• NSC Number: 113058
• DSSTox Substance ID: DTXSID40209994
• Nikkaji Number: J95.527B
• Wikidata: Q72462685
• ChEMBL ID: CHEMBL3741783
• Mol file: 611-79-0.mol

Synonyms:3,3'-Diaminobenzophenone;611-79-0;Bis(3-aminophenyl)methanone;Methanone, bis(3-aminophenyl)-;3,3'-diamino benzophenone;3,3//'-Diaminobenzophenone;EINECS 210-281-3;3-(3-aminobenzoyl)aniline;NSC113058;5224-16-8;CBMicro_014188;3,3/'-Diaminobenzophenone;3,3\'-Diaminobenzophenone;Oprea1_824643;SCHEMBL125621;Bis(3-aminophenyl)methanone #;CHEMBL3741783;DTXSID40209994;AMY31831;SMSF0004809;MFCD00014774;SC5083;3,3'-Diaminobenzophenone, >/=95%;AKOS001589460;CB11020;NSC 113058;NSC-113058;SB78940;BIS-(3-AMINO-PHENYL)-METHANONE;AC-20505;AS-54690;BIM-0014348.P001;CS-0156896;D1682;FT-0614039;A833078;AE-641/01976060;W-105185;3,5-bis(methoxycarbonyl)benzenesulfonate;tetrabutylphosphonium

Chemical Property of 3,3'-Diaminobenzophenone

Chemical Property:

• Appearance/Colour: yellow acicular crystal
• Melting Point: 150-151 °C
• Refractive Index: 1.6920 (estimate)
• Boiling Point: 469.4 °C at 760 mmHg
• PKA: 3.59±0.10(Predicted)
• Flash Point: 237.7 °C
• PSA: 69.11000
• Density: 1.233 g/cm³
• LogP: 3.24440
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Water Solubility.: Insoluble in water
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 212.094963011
• Heavy Atom Count: 16
• Complexity: 230

Purity/Quality:

99% ^*data from raw suppliers

3,3''-Diaminobenzophenone ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC(=C1)N)C(=O)C2=CC(=CC=C2)N

Technology Process of 3,3'-Diaminobenzophenone

There total 16 articles about 3,3'-Diaminobenzophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

3,3'-dinitrobenzophenone (21222-05-9) → 3,3'-diaminobenzophenone (611-79-0)

Guidance literature:

With tetrabutylammomium bromide; tin(ll) chloride; at 90 ℃; for 0.416667h;

DOI:10.1055/s-2004-830847

Reference yield: 87.0%

C16H18N2S2 → 3,3'-diaminobenzophenone (611-79-0)

Guidance literature:

With ammonium persulfate; Montmorillonite K-10 clay; for 0.0666667h; microwave irradiation;

DOI:10.1055/s-2004-817760

Reference yield: 83.0%

benzophenone (119-61-9) → 3,3'-diaminobenzophenone (611-79-0)

Guidance literature:

benzophenone; With dinitrogen pentoxide; In dichloromethane; at 30 ℃; for 5h; Molecular sieve;

With hydrogen; nickel; In dichloromethane; for 5h; under 11251.1 Torr; Temperature; Pressure;

upstream raw materials:

3,3'-dinitrobenzophenone

3-Nitrobenzyl alcohol

bis(3-nitrophenyl)methane

nitrobenzene

Downstream raw materials:

3,3'-diisocyanato-benzophenone

3,3'-dihydroxybenzophenone

3,3'-diaminobenzhydrol

3,3'-bis-(2-chloro-acetylamino)-benzophenone

Refernces

• 1、 -. "One-pot method for synthesizing 3, 3'-diamino benzophenone". Paragraph 0035-0044; 0050-0055; 0056-0061. . Retrieved 2019/03/23.
• 2、 Majumdar,Ghosh,Chakravorty. "Synthesis and characterization of symmetrical eight aromatic ring containing bent-shaped material derived from benzophenone". scheme or table. p. 63 - 72. Retrieved 2011/09/13.