Stannane, [[(diethylamino)thioxomethyl]thio]triphenyl-

Base Information

• Chemical Name: Stannane, [[(diethylamino)thioxomethyl]thio]triphenyl-
• CAS No.: 1803-18-5
• Molecular Formula: C23H25NS2Sn
• Molecular Weight: 498.2913
• NSC Number: 118039
• DSSTox Substance ID: DTXSID7075133
• Mol file: 1803-18-5.mol

Synonyms:1803-18-5;((Diethylthiocarbamoyl)thio)triphenylstannane;Stannane, [[(diethylamino)thioxomethyl]thio]triphenyl-;Stannane, (((diethylamino)thioxomethyl)thio)triphenyl-;triphenylstannyl N,N-diethylcarbamodithioate;NSC118039;Stannane, ((diethylthiocarbamoyl)thio)triphenyl-;DTXSID7075133;triphenyltin N,N-diethyldithiocarbamate;NSC 118039;NSC-118039

Chemical Property of Stannane, [[(diethylamino)thioxomethyl]thio]triphenyl-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 7
• Exact Mass: 499.045045
• Heavy Atom Count: 27
• Complexity: 402

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)C(=S)S[Sn](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Stannane, [[(diethylamino)thioxomethyl]thio]triphenyl-

There total 3 articles about Stannane, [[(diethylamino)thioxomethyl]thio]triphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

sodium N,N-diethyldithiocarbamate (148-18-5) + triphenyltin chloride (639-58-7) → (C6H5)3Sn(S2CN(C2H5)2) (1803-18-5)

Guidance literature:

In dichloromethane; byproducts: NaCl; addn. of the anhyd. sodium dithiocarbamate to soln. of triphenyltin chloride in CH2Cl2, stirring for 14 h at 30°C; filtration, concn. of filtrate under reduced pressure, pptn. by addn. ofether, recrystn. from dichloromethane-hexane; elem. anal.;

Reference yield: 60.0%

sodium N,N-diethyldithiocarbamate (148-18-5) + triphenyltin acetate (900-95-8) → (C6H5)3Sn(S2CN(C2H5)2) (1803-18-5)

Guidance literature:

In ethanol; chloroform; byproducts: NaCH3COO; in a dry box flushed with N2; mixing an alc./CHCl3 soln. of dithiocarbamate with Sn-compd. in alc., stirring for ca 2 h; elem. anal.;

Reference yield:

potassium diethyldithiocarbamate (3699-30-7) + triphenyltin chloride (639-58-7) → (C6H5)3Sn(S2CN(C2H5)2) (1803-18-5)

Guidance literature:

In dichloromethane; react. of appropriate mole ratios; not isolated, identified by NMR;

upstream raw materials:

sodium N,N-diethyldithiocarbamate

triphenyltin acetate

triphenyltin chloride

potassium diethyldithiocarbamate