8-Bromo-1,4-dioxaspiro[4.5]decane

Base Information

Chemical Name:8-Bromo-1,4-dioxaspiro[4.5]decane
CAS No.:68278-51-3
Molecular Formula:C8H13BrO2
Molecular Weight:221.094
Hs Code.:2932999099
European Community (EC) Number:828-304-6
Nikkaji Number:J2.857.409F
Mol file:68278-51-3.mol

Synonyms:8-bromo-1,4-dioxaspiro[4.5]decane;68278-51-3;MFCD11847479;1,4-Dioxaspiro[4.5]decane, 8-bromo-;SCHEMBL662249;JCWBPQVTECHCIP-UHFFFAOYSA-N;AKOS025148558;PB43275;AS-50835;SY155762;CS-0049964;EN300-132779;P11219;A897806

Suppliers and Price of 8-Bromo-1,4-dioxaspiro[4.5]decane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
8-bromo-1,4-dioxaspiro[4.5]decane
50mg
$ 110.00

SynQuest Laboratories
8-Bromo-1,4-dioxaspiro[4.5]decane
1 g
$ 1465.00

SynQuest Laboratories
8-Bromo-1,4-dioxaspiro[4.5]decane
250 mg
$ 595.00

ChemScene
8-Bromo-1,4-dioxaspiro[4.5]decane
250mg
$ 225.00

ChemScene
8-Bromo-1,4-dioxaspiro[4.5]decane
100mg
$ 135.00

ChemScene
8-Bromo-1,4-dioxaspiro[4.5]decane
1g
$ 450.00

ChemScene
8-Bromo-1,4-dioxaspiro[4.5]decane
10g
$ 1495.00

ChemScene
8-Bromo-1,4-dioxaspiro[4.5]decane
5g
$ 885.00

Chemenu
8-Bromo-1,4-dioxaspiro[4.5]decane 95%
1g
$ 622.00

American Custom Chemicals Corporation
8-BROMO-1,4-DIOXASPIRO[4.5]DECANE 95.00%
5MG
$ 501.68

Total 16 raw suppliers

Chemical Property of 8-Bromo-1,4-dioxaspiro[4.5]decane

Chemical Property:

Boiling Point:89-90 °C(Press: 5 Torr)
PSA：18.46000
Density:1.46±0.1 g/cm3(Predicted)
LogP:2.06700
Storage Temp.:2-8°C
XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:220.00989
Heavy Atom Count:11
Complexity:133

Purity/Quality:

99%, ^*data from raw suppliers

8-bromo-1,4-dioxaspiro[4.5]decane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2(CCC1Br)OCCO2

Technology Process of 8-Bromo-1,4-dioxaspiro[4.5]decane

There total 2 articles about 8-Bromo-1,4-dioxaspiro[4.5]decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 22428-87-1
4,4-ethylenedioxycyclohexan-1-ol

: 68278-51-3
8-bromo-1,4-dioxaspiro[4,5]decane

Guidance literature:: With carbon tetrabromide; triphenylphosphine; In dichloromethane; at 0 ℃; for 5h;

Reference yield:

: 4746-97-8
cyclohexanedione monoethylene ketal

: 68278-51-3
8-bromo-1,4-dioxaspiro[4,5]decane

Guidance literature:: Multi-step reaction with 2 steps

1: sodium tetrahydroborate / methanol / 1 h / 0 - 18 °C

2: carbon tetrabromide; triphenylphosphine / dichloromethane / 5 h / 0 °C / Inert atmosphere

With sodium tetrahydroborate; carbon tetrabromide; triphenylphosphine; In methanol; dichloromethane;

Reference yield: 85.0%

: 68278-51-3
8-bromo-1,4-dioxaspiro[4,5]decane

: 121386-57-0
methyl 2-phenylprop-2-en-1-yl carbonate

: 1373335-02-4
8-(2-phenylallyl)-1,4-dioxaspiro[4.5]decane

Guidance literature:: With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; magnesium chloride; 4,4',4-tri-tert-butyl-2,2':6',2-terpyridine; zinc; In N,N-dimethyl acetamide; at 80 ℃; for 12h; Inert atmosphere;
DOI:10.1002/chem.201102984