3-(3-(3-aminophenyl)-1-oxadiaziridin-2-yl)benzenamine

Base Information

• Chemical Name: 3-(3-(3-aminophenyl)-1-oxadiaziridin-2-yl)benzenamine
• CAS No.: 101-13-3
• Molecular Formula: C12H12 N4 O
• Molecular Weight: 228.253
• Hs Code.: 2927000090
• Mol file: 101-13-3.mol

Synonyms:Aniline,3,3'-azoxydi- (8CI); Benzenamine, 3,3'-azoxybis- (9CI); 3,3'-Azoxydianiline;3,3'-Diaminoazoxybenzene; NSC 7131; m,m'-Azoxybisaniline

Chemical Property of 3-(3-(3-aminophenyl)-1-oxadiaziridin-2-yl)benzenamine

Chemical Property:

• Vapor Pressure: 2.1E-10mmHg at 25°C
• Boiling Point: 507.1°Cat760mmHg
• Flash Point: 260.5°C
• PSA: 93.15000
• Density: 1.3g/cm³
• LogP: 4.46230

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-(3-(3-aminophenyl)-1-oxadiaziridin-2-yl)benzenamine

There total 13 articles about 3-(3-(3-aminophenyl)-1-oxadiaziridin-2-yl)benzenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

3-nitro-aniline (99-09-2) → 3,3'-diaminoazoxybenzene (101-13-3)

Guidance literature:

With potassium hydroxide; In methanol; toluene; for 0.5h; Heating;

Reference yield:

3-nitro-aniline (99-09-2) → m-phenylenediamine (108-45-2,64554-26-3,76583-20-5) + 3,3'-diaminoazobenzene + 3,3'-diaminoazoxybenzene (101-13-3)

Guidance literature:

With hydrazine hydrate; Pd/C; In ethanol; water; at 80 ℃; for 10h; chemoselective reaction;

DOI:10.1039/c3ta00159h

Reference yield:

3-nitro-aniline (99-09-2) + hydrazine (302-01-2,78206-91-4,119775-10-9,75013-58-0) → m-phenylenediamine (108-45-2,64554-26-3,76583-20-5) + 3,3'-diaminoazoxybenzene (101-13-3)

Guidance literature:

DOI:10.1557/JMR.2000.0371

upstream raw materials:

D-glucose

3-nitro-aniline

3,3'-dinitro azoxybenzene

hydrazine

Downstream raw materials:

bis-(3-acetylamino-phenyl)-diazene-N-oxide

3,3'-Azoxy-di-phenol

3,3'-diaminoazobenzene

m-phenylenediamine

Refernces

• 1、 Lu, Yong-Ming,Zhu, Hai-Zhou,Li, Wei-Gu,Hu, Bo,Yu, Shu-Hong. "Size-controllable palladium nanoparticles immobilized on carbon nanospheres for nitroaromatic hydrogenation". . p. 3783 - 3788. Retrieved 2013.
• 2、 Prato, Maurizio,Quintily, Ugo,Scapol, Lucia,Scorrano, Gianfranco. "The synthesis of anilines or azoxybenzenes from the reduction of nitrobenzenes in basic alcoholic media". . p. 99 - 102. Retrieved 2007/10/02.