Hydrazine, 1-methyl-1,2-diphenyl-

Base Information

• Chemical Name: Hydrazine, 1-methyl-1,2-diphenyl-
• CAS No.: 37682-91-0
• Molecular Formula: C₁₃H₁₄N₂
• Molecular Weight: 198.268
• DSSTox Substance ID: DTXSID10191115
• Nikkaji Number: J2.984.046F
• Wikidata: Q83063603
• Mol file: 37682-91-0.mol

Synonyms:N-Methylhydrazobenzene;Hydrazine, 1-methyl-1,2-diphenyl-;37682-91-0;1,2-Diphenyl-1-methylhydrazine;SCHEMBL2744596;DTXSID10191115

Chemical Property of Hydrazine, 1-methyl-1,2-diphenyl-

Chemical Property:

• XLogP3: 3.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 198.115698455
• Heavy Atom Count: 15
• Complexity: 169

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C1=CC=CC=C1)NC2=CC=CC=C2

Technology Process of Hydrazine, 1-methyl-1,2-diphenyl-

There total 21 articles about Hydrazine, 1-methyl-1,2-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

N-phenyl-N-hydroxy-2,2-dimethylpropanamide (111750-22-2) + N-methylaniline (100-61-8) → N-methyl-N,N′-diphenylhydrazine (37682-91-0)

Guidance literature:

With triethylamine; at 80 ℃; for 2h;

Reference yield: 90.0%

N-(Acetoxy)anilin (71825-04-2) + N-methylaniline (100-61-8) → N-methyl-N,N′-diphenylhydrazine (37682-91-0)

Guidance literature:

at 20 ℃; for 5h;

Reference yield: 85.0%

diphenyl hydrazine (122-66-7) + methyl iodide (74-88-4) → N-methyl-N,N′-diphenylhydrazine (37682-91-0)

Guidance literature:

diphenyl hydrazine; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - -60 ℃; for 0.25h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; hexane; at -60 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1039/c1ob05328k

upstream raw materials:

dimethyl sulfate

diphenyl hydrazine

Azobenzene

methyl iodide

Downstream raw materials:

N-methylaniline

1-(phenylamino)naphthalen-2-ol

aniline

Azobenzene