4'-Methoxy-4-nitroazobenzene

Base Information

• Chemical Name: 4'-Methoxy-4-nitroazobenzene
• CAS No.: 29418-59-5
• Molecular Formula: C13H11 N3 O3
• Molecular Weight: 257.249
• Hs Code.: 2927000090
• European Community (EC) Number: 688-684-2
• NSC Number: 86534
• DSSTox Substance ID: DTXSID201037888
• Nikkaji Number: J2.001.375C,J84.800J,J2.072.478A
• Mol file: 29418-59-5.mol

Synonyms:4'-Methoxy-4-nitroazobenzene;29418-59-5;Azobenzene, 4'-methoxy-4-nitro-;NSC 86534;BRN 0918879;3-16-00-00089 (Beilstein Handbook Reference);1-(4-methoxyphenyl)-2-(4-nitrophenyl)diazene;NSC86534;NCIOpen2_005118;4-Methoxy-4'-nitroazobenzene;4-(4'-Nitrophenylazo)anisole;4-nitro-4'-methoxy-azobenzene;SCHEMBL3284432;SCHEMBL13101803;DTXSID201037888;(E)-4-Methoxy-4'-nitroazobenzene;(Z)-4-Methoxy-4'-nitroazobenzene;NSC-86534;AKOS024337879;LS-23460;(e)-(4-methoxyphenyl)(4-nitrophenyl)diazene;Diazene, 1-(4-methoxyphenyl)-2-(4-nitrophenyl)-

Chemical Property of 4'-Methoxy-4-nitroazobenzene

Chemical Property:

• Vapor Pressure: 2.42E-07mmHg at 25°C
• Boiling Point: 434.4°Cat760mmHg
• Flash Point: 216.5°C
• PSA: 79.77000
• Density: 1.25g/cm³
• LogP: 4.54200
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 3
• Exact Mass: 257.08004122
• Heavy Atom Count: 19
• Complexity: 314

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)N=NC2=CC=C(C=C2)[N+](=O)[O-]

Technology Process of 4'-Methoxy-4-nitroazobenzene

There total 10 articles about 4'-Methoxy-4-nitroazobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

(4-methoxyphenyl)trimethylstannane (940-00-1) + 4-nitrobenzenediazonium tetrafluoroborate (456-27-9) → 4-(4'-nitrophenylazo)anisole (29418-59-5)

Guidance literature:

In acetonitrile; for 7h; Ambient temperature;

Reference yield: 10.0%

4-nitrobenzenediazonium tetrafluoroborate (456-27-9) + methoxybenzene (100-66-3) → 4-(4'-nitrophenylazo)anisole (29418-59-5)

Guidance literature:

With sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate; In dichloromethane; water; for 48h; Ambient temperature;

DOI:10.1246/bcsj.56.796

Reference yield:

C13H13N3O3 → 4-(4'-nitrophenylazo)anisole (29418-59-5)

Guidance literature:

With sodium hypochlorite; In dichloromethane; at 20 ℃; for 5h; Green chemistry;

upstream raw materials:

diazomethane

4-(4'-hydroxyphenylazo)nitrobenzene

(4-methoxyphenyl)trimethylstannane

4-nitrobenzenediazonium tetrafluoroborate

Downstream raw materials:

2,4-dinitroanisole

4-nitrobenzenediazonium chloride

4-nitro-benzenediazonium; bromide

p-Nitrophenyldiazonium-perbromid