4-Nitrobenzenediazonium chloride

Base Information

• Chemical Name: 4-Nitrobenzenediazonium chloride
• CAS No.: 100-05-0
• Deprecated CAS: 1148018-41-0,1489238-97-2,1581883-57-9,1773542-06-5,1867184-90-4,1943681-24-0,2135826-39-8,22719-23-9,2170108-21-9,2176485-54-2,2231733-43-8,2231764-70-6,2390149-70-7,2412913-66-5,2629857-87-8
• Molecular Formula: C6H4ClN3O2
• Molecular Weight: 185.57
• Hs Code.: 2927000090
• European Community (EC) Number: 202-814-3
• UNII: 0T2HNH603P
• DSSTox Substance ID: DTXSID20883291
• Mol file: 100-05-0.mol

Synonyms:4-nitrophenyldiazonium;4-nitrophenyldiazonium chloride;4-nitrophenyldiazonium fluoroborate;4-nitrophenyldiazonium iodide;4-nitrophenyldiazonium nitrate;4-nitrophenyldiazonium, nitride (3:1);p-nitrophenyldiazonium;p-nitrophenyldiazonium chloride;p-nitrophenyldiazonium fluoroborate;para-nitrophenyldiazonium

Chemical Property of 4-Nitrobenzenediazonium chloride

Chemical Property:

• Melting Point: 243-243.5 °C
• PSA: 73.97000
• LogP: -0.39342
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 184.9992041
• Heavy Atom Count: 12
• Complexity: 194

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1[N+]#N)[N+](=O)[O-].[Cl-]

Technology Process of 4-Nitrobenzenediazonium chloride

There total 41 articles about 4-Nitrobenzenediazonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

→ 4-nitrobenzenediazonium chloride (100-05-0)

Guidance literature:

With hydrogenchloride; oxygen; nitrogen(II) oxide; In water; at 20 ℃; for 0.5h;

Reference yield: 100.0%

4-nitro-aniline (100-01-6,104810-17-5) → 4-nitrobenzenediazonium chloride (100-05-0)

Guidance literature:

With nitrosylchloride; for 24h; under 750.075 Torr;

DOI:10.1002/1521-3765(20020315)8:6<1395::AID-CHEM1395>3.0.CO;2-L

Reference yield: 82.0%

4-Nitro-N-(trimethylsilyl)anilin (63911-89-7) → Trimethylsilanol (1066-40-6) + trimethyl(isopentyloxy)silane (18246-56-5) + 4-nitrobenzenediazonium chloride (100-05-0)

Guidance literature:

With chloro-trimethyl-silane; isopentyl nitrite; In dichloromethane; for 10h; Ambient temperature;

upstream raw materials:

hydrogenchloride

4-nitro-aniline

isopentyl nitrite

acetyl chloride

Downstream raw materials:

1-(4-nitrophenyl)-1H-tetrazole

N-(4-nitro-phenyl)-N'-m-tolyl-triazene

chloro-(4-nitro-phenylhydrazono)-acetic acid ethyl ester

1,1-bis-(4-nitro-phenylazo)-2,2-diphenyl-ethene

Refernces

• 1、 Abdallah, Sanaa O.,Metwally, Nadia H.,Anwar, Hany F.,Elnagdi, Mohamed H.. "Synthesis and chemical reactivity of 3-oxo-2-arylhydrazono-propanenitriles". . p. 781 - 786. Retrieved 2005.
• 2、 Zhao, Xiao-Jun,Cui, Zhi-Hua,Wang, Ren-Liang,Li, Xin,Fan, Su-Ju,Chen, Wei-Guo. "Synthesis of an electron-rich aniline-containing dye and its dyeing behaviors on silk through a three-component Mannich-type reaction". . p. 259 - 262. Retrieved 2015.
• 3、 Abdelhamid, Abdou O.,Gomha, Sobhi M.. "Synthesis and characterization of new pyrazole-based thiazoles". . p. 1409 - 1414. Retrieved 2017.
• 4、 Chung, Yunmi,Lee, Hanna,Kyo, Han Ahn. "N-acyl triazenes as tunable and selective chemodosimeters toward cyanide ion". . p. 9470 - 9474. Retrieved 2006.
• 5、 Heinisch,Holzer,Nawwar. "Pyridazines. XXVI. A novel synthesis of pyrano[2,3-d]pyridazines". . p. 93 - 96. Retrieved 1986.
• 6、 Coelho, Paulo J.,Lup, Andrew Ng Kay,Mahon, Peter J.,Pesyan, Nader Noroozi,Ramezanitaghartapeh, Mohammad,Raposo, M. Manuela M.,Rashidnejad, Hamid,Soltani, Alireza. "A comprehensive spectroscopic, solvatochromic and photochemical analysis of 5-hydroxyquinoline and 8-hydroxyquinoline mono-azo dyes". . . Retrieved 2020/10/06.