2-Cyclohexen-1-one, 3-(trimethylstannyl)-

Base Information

Chemical Name:2-Cyclohexen-1-one, 3-(trimethylstannyl)-
CAS No.:69519-95-5
Molecular Formula:C₉H₁₆OSn
Molecular Weight:258.935
Hs Code.:

Synonyms:

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Chemical Property of 2-Cyclohexen-1-one, 3-(trimethylstannyl)-

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Technology Process of 2-Cyclohexen-1-one, 3-(trimethylstannyl)-

There total 2 articles about 2-Cyclohexen-1-one, 3-(trimethylstannyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: lithium (phenylthio)(trimethylstannyl)cuprate

: 56671-82-0
3-Iodocyclohex-2-enone

: 69519-95-5
3-trimethylstannyl-2-cyclohexen-1-one

Guidance literature:: In tetrahydrofuran; a cold (-20°C) stirred soln. of the cuprate reagent was allowed to react with β-iodo enone in dry THF; the mixt. was stirred under dry Ar atm. at -20°C for 15 min and at room temp. for 30 min;; chromy. (in mixt. of methanol and diethyl ether) followed by the elution with diethyl ether; removal of the solvent by distn. (air-bath temp. 65-80°C/0.09 Torr);;

Reference yield: 32.0%

: 56671-82-0
3-Iodocyclohex-2-enone

: 17946-71-3
lithium trimethylstannyl

: 112080-43-0
3,3-bis(trimethylstannyl)cyclohexanone

: 69519-95-5
3-trimethylstannyl-2-cyclohexen-1-one

Guidance literature:: In tetrahydrofuran; a cold (-78°C) stirred soln. of trimethylstannyl-lithium in dry THF was allowed to react with 3-iodo-2-cyclohexen-1-one in dry THF; the mixt. was stirred under dry argon atm. at -78°C for 1 h;; satd. aq. NH4Cl (pH 8) and diethyl ether were added and the mixt. was stirred for several min.; the organic layer was sepd., washed with brine and dried (MgSO4); removal of the solvent and sepn. of compds. by distn. glc anal.; elem. anal.;