3-(Methylthio)acrylic acid, (Z)-

Base Information

Chemical Name:3-(Methylthio)acrylic acid, (Z)-
CAS No.:70424-09-8
Molecular Formula:C4H6O2S
Molecular Weight:118.15400
Hs Code.:
UNII:64HJ4VMD4C
Nikkaji Number:J175.469F
Mol file:70424-09-8.mol

Synonyms:cis-Thiomethyl acrylic acid;64HJ4VMD4C;3-(Methylthio)acrylic acid, (Z)-;(Z)-3-Methylsulfanylprop-2-enoic acid;2-Propenoic acid, 3-(methylthio)-, (Z)-;2-Propenoic acid, 3-(methylthio)-, (2Z)-;70424-09-8;UNII-64HJ4VMD4C;SCHEMBL18300812;(z)-3-(methylthio)-propenoic acid

Suppliers and Price of 3-(Methylthio)acrylic acid, (Z)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 3-(Methylthio)acrylic acid, (Z)-

Chemical Property:

PSA：62.60000
LogP:0.94770
XLogP3:0.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:118.00885060
Heavy Atom Count:7
Complexity:87.7

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CSC=CC(=O)O
Isomeric SMILES:CS/C=C\C(=O)O

Technology Process of 3-(Methylthio)acrylic acid, (Z)-

There total 6 articles about 3-(Methylthio)acrylic acid, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 74-93-1
methylthiol

: 471-25-0
Propiolic acid

: 26398-93-6,26995-94-8
(E)-β-methylthiopropenoic acid

: 70424-09-8,26995-94-8
(Z)-β-methylthiopropenoic acid

Guidance literature:: With 1,4-diaza-bicyclo[2.2.2]octane; 1.) 85 deg C, 60 atm (sealed tube), 12 h; 2.) xylene, reflux, 24 h;
DOI:10.1016/S0040-4020(01)80647-5

Reference yield: 63.0%

: 131424-34-5
3c-thiocyanato-acrylic acid

: 74-88-4
methyl iodide

: 70424-09-8,26995-94-8
(Z)-β-methylthiopropenoic acid

Guidance literature:: With sodium hydroxide; In methanol; for 0.5h; Ambient temperature;

Reference yield: 8.0%

: 74-93-1
methylthiol

: 471-25-0
Propiolic acid

: 26398-93-6,26995-94-8
(E)-β-methylthiopropenoic acid

: 70424-09-8,26995-94-8
(Z)-β-methylthiopropenoic acid

: 95902-00-4
3,3-bis(methylthio)propionic acid

Guidance literature:: With 1,4-diaza-bicyclo[2.2.2]octane; at 80 - 90 ℃; for 12h; Yield given. Title compound not separated from byproducts; in Pyrex tube;
DOI:10.1248/cpb.37.1932