Methyl 3-amino-2-hydroxy-5-methylbenzoate

Base Information

Chemical Name:Methyl 3-amino-2-hydroxy-5-methylbenzoate
CAS No.:70978-07-3
Molecular Formula:C9H11NO3
Molecular Weight:181.191
Hs Code.:2922509090
DSSTox Substance ID:DTXSID60502979
Wikidata:Q82356437
Mol file:70978-07-3.mol

Synonyms:70978-07-3;Methyl 3-amino-2-hydroxy-5-methylbenzoate;Methyl 3-amino-2-hydroxy-5-methylbenzenecarboxylate;Benzoic acid, 3-amino-2-hydroxy-5-methyl-, methyl ester;METHYL 3-AMINO-2-HYDROXY-5-METHYLBENZOATE 95+%;SCHEMBL11071838;DTXSID60502979;VCA97807;MFCD14560550;AKOS005073750;ND-0035;Methyl3-amino-2-hydroxy-5-methylbenzoate;CS-0326574;FT-0681721;A866514;J-522127;Methyl 3-amino-2-hydroxy-5-methylbenzoate, AldrichCPR

Suppliers and Price of Methyl 3-amino-2-hydroxy-5-methylbenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

SynQuest Laboratories
Methyl 3-amino-2-hydroxy-5-methylbenzoate 95.0%
1 g
$ 296.00

SynQuest Laboratories
Methyl 3-amino-2-hydroxy-5-methylbenzoate 95.0%
500 mg
$ 232.00

Matrix Scientific
Methyl 3-amino-2-hydroxy-5-methylbenzenecarboxylate >95%
1g
$ 304.00

Matrix Scientific
Methyl 3-amino-2-hydroxy-5-methylbenzenecarboxylate >95%
500mg
$ 244.00

Crysdot
Methyl3-amino-2-hydroxy-5-methylbenzoate 95+%
5g
$ 677.00

Chemcia Scientific
3-Amino-2-hydroxy-5-methyl-benzoicacidmethylester 95%
1 G
$ 235.00

American Custom Chemicals Corporation
METHYL-3-AMINO-2-HYDROXY-5-METHYLBENZENECARBOXYLATE 95.00%
5MG
$ 502.38

AK Scientific
Methyl3-amino-2-hydroxy-5-methylbenzenecarboxylate
500mg
$ 379.00

Total 9 raw suppliers

Chemical Property of Methyl 3-amino-2-hydroxy-5-methylbenzoate

Chemical Property:

PSA：72.55000
LogP:1.65060
XLogP3:1.7
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:181.07389321
Heavy Atom Count:13
Complexity:195

Purity/Quality:

97% ^*data from raw suppliers

Methyl 3-amino-2-hydroxy-5-methylbenzoate 95.0% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C(=C1)N)O)C(=O)OC

Technology Process of Methyl 3-amino-2-hydroxy-5-methylbenzoate

There total 3 articles about Methyl 3-amino-2-hydroxy-5-methylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 67191-44-0
methyl 2-hydroxy-5-methyl-3-nitrobenzoate

: 70978-07-3
methyl 3-amino-2-hydroxy-5-methylbenzoate

Guidance literature:: With iron; ammonium chloride; In toluene; at 85 - 90 ℃; for 1h;
DOI:10.1248/cpb.40.624

Reference yield:

: 22717-57-3
methyl 6-hydroxy-m-toluate

: 70978-07-3
methyl 3-amino-2-hydroxy-5-methylbenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 24 percent / conc. HNO₃, conc. H₂SO₄ / -20 °C

2: 58 percent / H₂ / 5percent Pd/C / ethanol

With sulfuric acid; hydrogen; nitric acid; palladium on activated charcoal; In ethanol;
DOI:10.1021/jm00154a019

Reference yield:

: 59672-93-4
2-hydroxy-5-methyl-3-nitro-benzoic acid

: 70978-07-3
methyl 3-amino-2-hydroxy-5-methylbenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: sulfuric acid / Heating

2: hydrogen / palladium on activated charcoal / ethanol

With sulfuric acid; hydrogen; palladium on activated charcoal; In ethanol;