AZO-TERT-BUTANE

Base Information

• Chemical Name: AZO-TERT-BUTANE
• CAS No.: 927-83-3
• Molecular Formula: C8H18 N2
• Molecular Weight: 142.244
• Hs Code.: 2927000090
• Mol file: 927-83-3.mol

Synonyms:Azoethane,1,1,1',1'-tetramethyl- (6CI,7CI,8CI); Diazene, bis(1,1-dimethylethyl)- (9CI);2,2'-Azobis(2-methylpropane); 2,2'-Azobis-tert-butane; 2,2'-Azoisobutane;Bis(tert-butyl)diimine; Di-tert-butyldiazene

Chemical Property of AZO-TERT-BUTANE

Chemical Property:

• Melting Point: -14.5°C
• Refractive Index: n20/D 1.397(lit.)
• Boiling Point: 150.5°Cat760mmHg
• Flash Point: 36°C
• PSA: 24.72000
• Density: 0.8g/cm³
• LogP: 3.03560
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,2′-Azobis(2-methylpropane) 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn
• Statements: 11-20/22-36/37/38
• Safety Statements: 16-26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of AZO-TERT-BUTANE

There total 14 articles about AZO-TERT-BUTANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

1,2-di-tert-butylhydrazine (13952-69-7) → di-t-butyldiazene (927-83-3)

Guidance literature:

at 20 ℃; for 72h; Air; Darkness;

DOI:10.1055/s-0030-1257868

Reference yield: 1.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + t-butylnitrite (917-95-3) → di-t-butyldiazene (927-83-3) + 1,3-di-tert-butylcarbodiimide (691-24-7) + 1,3-di-tert-butylurea (5336-24-3) + di-t-butyldiazene N-oxide (16649-52-8,54168-23-9,87339-11-5)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); Stirring of nitroso compound in THF under N2, metal carbonyl in THF is added, the soln. is irradiated for 1 h (sunlamp photolysis) at 30°C.; addn. of naphthalene as internal standard, Gc-anal.;

DOI:10.1016/0022-328X(89)80121-4

Reference yield:

tert-butylamine (75-64-9) → di-t-butyldiazene (927-83-3) + N-Phenylhydroxylamine (100-65-2) + azoxybenzene (495-48-7,55599-32-1)

Guidance literature:

With nitrobenzene; Irradiation; also in presence of biacetyl and benzophenone;

upstream raw materials:

N-bromo-2-methylpropan-2-amine

tert.-butyl lithium

nitrobenzene

tert-butylamine

Downstream raw materials:

1,2-di-p-tolylethane

4-methyl-1-(2,2-dimethylpropyl)benzene

(2,2-dimethyl-1-propyl)benzene

4-methylbibenzyl

Refernces

• 1、 Misra, Rohit,Neti, Nageswara Nao,Dionysiou, Dionysios D.,Tandekar, Mahendra,Kanade, Gajanan S.. "Novel integrated carbon particle based three dimensional anodes for the electrochemical degradation of reactive dyes". . p. 10799 - 10808. Retrieved 2015/02/05.
• 2、 Quast, Helmut,Schmitt, Edeltraud,Ross, Karl-Heinz. "1-acylsemicarbazides by ring opening of iminodiaziridines with carboxylic acids: Novel, expeditious access to the azapeptide motif". experimental part. p. 3358 - 3362. Retrieved 2010/11/16.