Benzenamine, 2-(1-methyl-2-butenyl)-, (E)-

Base Information

• Chemical Name: Benzenamine, 2-(1-methyl-2-butenyl)-, (E)-
• CAS No.: 74266-80-1
• Molecular Formula: C11H15N
• Molecular Weight: 161.247
• Mol file: 74266-80-1.mol

Synonyms:

Chemical Property of Benzenamine, 2-(1-methyl-2-butenyl)-, (E)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenamine, 2-(1-methyl-2-butenyl)-, (E)-

There total 12 articles about Benzenamine, 2-(1-methyl-2-butenyl)-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

N-(1'-methyl-2'-butenyl)aniline (37857-41-3) → {2-[(2E)-1-methylbut-2-en-1-yl]phenyl}amine (74266-80-1)

Guidance literature:

With toluene-4-sulfonic acid; In 5,5-dimethyl-1,3-cyclohexadiene; at 145 ℃; for 7h; regioselective reaction;

DOI:10.1134/S1070363216040083

Reference yield: 86.0%

trans-N-(pent-3-en-2-yl)aniline (37857-41-3,72792-45-1,72792-46-2) → {2-[(2E)-1-methylbut-2-en-1-yl]phenyl}amine (74266-80-1)

Guidance literature:

With hydrogenchloride; In 5,5-dimethyl-1,3-cyclohexadiene; at 145 ℃;

DOI:10.1002/jhet.3861

Reference yield: 68.0%

trans-N-(pent-3-en-2-yl)aniline (37857-41-3,72792-45-1,72792-46-2) → {2-[(2E)-1-methylbut-2-en-1-yl]phenyl}amine (74266-80-1) + 4-[(2E)-1-methylbut-2-en-1-yl]aniline (74266-81-2) + 2,6-di(1-methyl-2-butenyl)aniline (83191-32-6) + aniline (62-53-3)

Guidance literature:

With aluminium trichloride; In nitrobenzene; at 130 ℃; Product distribution; other Lewis acids or aniline hydrochloride; other solvents;

upstream raw materials:

trans-N-(pent-3-en-2-yl)aniline

o-toluidine hydrochloride

(E)-4-chloropent-2-ene

aniline

Downstream raw materials:

2-ethyl-2-methyl-2,3-dihydro-1H-indole

4,4-Dimethyl-1-aminoindane

N-benzoyl-2-(2-hydroxy-1-methylethyl)aniline

(3-methyl-1H-indol-1-yl)(phenyl)methanone

Refernces

• 1、 Aleksandrova,Abdullin,Vakhitova, Yu. V.,Gataullin. "Approach to preparative synthesis of ortho-(1-methylbut-2-en-1-yl)anilines, precursors of new cytotoxic heterocycles". . p. 810 - 814. Retrieved 2016/06/13.
• 2、 Abdrakhmanov, I. B.,Saraeva, Z. N.,Nigmatullin, N. G.,Tolstikov, G. A.. "CATALYTIC EFFECTS IN THE CLAISEN AMINO REARRANGEMENT". . p. 1552 - 1554. Retrieved 2007/10/02.