74266-81-2Relevant academic research and scientific papers
Thermal intramolecular transformation of key intermediates in the photooxidation of para -allyl-substituted phenyl azide
Chainikova, Ekaterina M.,Pankratyev, Evgeniy Yu.,Teregulova, Aigul N.,Gataullin, Rail R.,Safiullin, Rustam L.
, p. 2728 - 2737 (2013)
The electronic spectra, kinetic regularities, and the mechanism of decay of the cis and trans isomeric forms of 4-[(2E)-1-methylbut-2-en-1-yl]phenylnitroso oxide (2) were studied by flash photolysis and product analysis. The mechanism of the consumption o
Synthesis of nitrogen-containing heterocyclic compounds by photooxidation of aromatic azides
Chainikova, Ekaterina,Safiullin, Rustam,Spirikhin, Leonid,Erastov, Alexey
supporting information, p. 2140 - 2142 (2013/06/26)
It is shown that the photolysis of certain aromatic azides in the presence of oxygen leads to the formation of nitrogen-containing heterocyclic compounds via a domino reaction sequence.
Alkenylation of anilines with dicyclopentadiene, cyclopentadiene, and piperylene
Gataullin,Kazhanova,Sagitdinov,Galyautdinov,Fatykhov,Spirikhin,Abdrakhmanov
, p. 280 - 285 (2007/10/03)
Alkenylation of anilines with dicyclopentadiene, cyclopentadiene, and piperylene in the presence of mineral acids and Lewis acids was studied.
ACID-CATALYZED RERRANGEMENT OF N-(1-METHYL-2-BUTENYL)ANILINE
Abdrakhmanov, I.B.,Sharafutdidov, V.M.,Tolstikov, G.A.
, p. 562 - 564 (2007/10/02)
The effect of the nature of the solvents and catalysts on the rerrangement of N-(1-methyl-2-butenyl)aniline was studied..The reaction is catalyzed by the hydrochlorides of aromatic amines and by Lewis acids.The nature of the solvents has an insignificant effect on the course of the rearrangement.
AMINO-CLAISEN REARRANGEMENT AS A METHOD FOR THE SYNTHESIS OF C-SUBSTITUTED ANILINES
Abdrakhmanov, I. B.,Sharafutdinov, V. M.,Nigmatullin, N. G.,Sagitdinov, I. A.,Tolstikov, G. A.
, p. 1278 - 1283 (2007/10/02)
Various C-alkenylanilines were synthesized by an amino-Claisen rearrangement.The composition of the rearrangement products is affected by the nature of the substituents in the benzene ring and at the nitrogen atom of the initial anilines.
