Stannane, (2,4-dinitrophenyl)trimethyl-

Base Information

Chemical Name:Stannane, (2,4-dinitrophenyl)trimethyl-
CAS No.:76074-20-9
Molecular Formula:C9H12N2O4Sn
Molecular Weight:330.915
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Stannane, (2,4-dinitrophenyl)trimethyl-

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of Stannane, (2,4-dinitrophenyl)trimethyl-

There total 3 articles about Stannane, (2,4-dinitrophenyl)trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 709-49-9
1-iodo-2,4-dinitrobenzene

: 661-69-8
hexamethyldistannane

: 76074-20-9
1-trimethylstannyl-2,4-dinitrobenzene

Guidance literature:: dichloro bis(acetonitrile) palladium(II); In N,N-dimethyl-formamide; byproducts: (CH3)3SnI; Me6Sn2, 2,4-(NO2)2C6H3I dissolved in DMF in a flask, catalyst added with stirring, reacted for 5 min at 20°C; water added, extracted with ether, extracts filtered, washed with water, dried with Na2SO4, chromy.(silica gel, hexane/ether 2:1);

Reference yield: 68.5%

: 709-49-9
1-iodo-2,4-dinitrobenzene

: 661-69-8
hexamethyldistannane

: 594-27-4
tetramethylstannane

: 76074-20-9
1-trimethylstannyl-2,4-dinitrobenzene

Guidance literature:: bis(η3-allyl-μ-chloropalladium(II)); In N,N,N,N,N,N-hexamethylphosphoric triamide; byproducts: (CH3)3SnI; Me6Sn2, 2,4-(NO2)2C6H3I dissolved in a flask, catalyst added with stirring, reacted for 10 min at 25°C; water added, extracted with ether, extracts filtered, washed with water, dried with Na2SO4, chromy.(silica gel, hexane/ether 2:1);

Reference yield: 35.0%

: 709-49-9
1-iodo-2,4-dinitrobenzene

: 1066-45-1
trimethyltin(IV)chloride

: 591-51-5
phenyllithium

: 76074-20-9
1-trimethylstannyl-2,4-dinitrobenzene

Guidance literature:: With carbon dioxide; In tetrahydrofuran; (Ar); the stannane is melted and added dropwise to PhLi and IC6H3(NO)2 in THF; temp. held below -100°C, mixt. stirred at -105°C for 4 h; CO2 bubbled through soln. for 15 min, soln. warmed to room temp.; addn. of water; extn. (ether), solvent removed in vac.; fractionated distn., chromy. (SiO2, CH2Cl2/petroleum ether), elem. anal.;