Zinc bromide heptan-1-ide (1/1/1)

Base Information

• Chemical Name: Zinc bromide heptan-1-ide (1/1/1)
• CAS No.: 7608-06-2
• Molecular Formula: C7H15BrZn
• Molecular Weight: 244.49
• DSSTox Substance ID: DTXSID80584196
• Mol file: 7608-06-2.mol

Synonyms:zinc;heptane;bromide;Zinc bromide heptan-1-ide (1/1/1);7608-06-2;DTXSID80584196

Chemical Property of Zinc bromide heptan-1-ide (1/1/1)

Chemical Property:

• Boiling Point: 65oC
• Flash Point: -17oC
• PSA: 0.00000
• Density: 0.965 g/mL at 25oC
• LogP: -0.20760
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 241.96485
• Heavy Atom Count: 9
• Complexity: 23.2

Purity/Quality:

99% ^*data from raw suppliers

1-Heptylzincbromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xn
• Hazard Codes: F,Xn
• Statements: 11-19-20/21/22-36/37/38-40-36/37
• Safety Statements: 16-26-33-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC[CH2-].[Zn+2].[Br-]

Technology Process of Zinc bromide heptan-1-ide (1/1/1)

There total 2 articles about Zinc bromide heptan-1-ide (1/1/1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Bromoheptane (629-04-9) + zinc (7440-66-6) → n-heptylzinc bromide (7608-06-2)

Guidance literature:

zinc; With iodine; In N,N-dimethyl acetamide; at 20 ℃; for 0.166667h;

1-Bromoheptane; In N,N-dimethyl acetamide; at 80 ℃; for 3h;

DOI:10.1021/jm301304e

Reference yield:

→ n-heptylzinc bromide (7608-06-2)

Guidance literature:

Zink-Kupfer-Verb. , Heptylbromid;

Reference yield: 90.0%

diphenylmethylsilanecarboxylic acid (18414-58-9) + n-heptylzinc bromide (7608-06-2) + benzylamine (100-46-9) → N-benzyloctanoic amide (70659-87-9)

Guidance literature:

n-heptylzinc bromide; With (2-morpholino-N-(quinolin-8-yl)acetamido)nickel(II) chloride; In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere; Glovebox;

diphenylmethylsilanecarboxylic acid; benzylamine; With potassium fluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; N,N-dimethyl-formamide; at 20 ℃; for 2h; Inert atmosphere; Sealed tube; Glovebox;

DOI:10.1002/chem.201804077

upstream raw materials:

1-Bromoheptane

zinc

Downstream raw materials:

tetradecane

1,4-diheptylbenzene

pentadecane

N-benzyloctanoic amide