diphenylmethylsilanecarboxylic acid

Base Information

• Chemical Name: diphenylmethylsilanecarboxylic acid
• CAS No.: 18414-58-9
• Molecular Formula: C₁₄H₁₄O₂Si
• Molecular Weight: 242.349
• Mol file: 18414-58-9.mol

Synonyms:diphenylmethylsilanecarboxylic acid

Chemical Property of diphenylmethylsilanecarboxylic acid

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenylmethylsilanecarboxylic acid

There total 2 articles about diphenylmethylsilanecarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

carbon dioxide (124-38-9,18923-20-1) + chloromethyldiphenylsilane (144-79-6) → diphenylmethylsilanecarboxylic acid (18414-58-9)

Guidance literature:

chloromethyldiphenylsilane; With lithium; In tetrahydrofuran; at 20 ℃; for 5h; Inert atmosphere;

carbon dioxide; In tetrahydrofuran; at -78 ℃; for 0.333333h; Inert atmosphere;

DOI:10.1021/ja208652n

Reference yield:

→ diphenylmethylsilanecarboxylic acid (18414-58-9)

Guidance literature:

DOI:10.1039/J19680003119

Reference yield: 98.0%

diphenylmethylsilanecarboxylic acid (18414-58-9) + 3,4-dichlorobenzyl bromide (18880-04-1) → 3,4-dichlorophenyl acetic acid (5807-30-7)

Guidance literature:

With lithium trimethylsilanolate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In 1,4-dioxane; at 80 ℃; for 16h; Glovebox;

DOI:10.1021/ol4003465

upstream raw materials:

carbon dioxide

chloromethyldiphenylsilane

Downstream raw materials:

2Zn⁽²⁺⁾*4(C₆H₅)2Si(CH₃)COO^(1-)*H₂O = [Zn(O₂CSi(C₆H₅)2(CH₃))2*0.5H₂O]2

[Cu((C₆H₅)2Si(CH₃)COO)2(H₂O)]2

NSC 158166

methyl 5-(4-(cyclopropanecarbonyl)piperazine-1-carbonyl)-2-(methoxymethoxy)benzoate