Ammonium diethylcarbamodithioate

Base Information

• Chemical Name: Ammonium diethylcarbamodithioate
• CAS No.: 21124-33-4
• Molecular Formula: C5H11 N S2 . H3 N
• Molecular Weight: 166.312
• Hs Code.: 2930909090
• European Community (EC) Number: 244-224-9
• Mol file: 21124-33-4.mol

Synonyms:Ammonium diethyldithiocarbamate;21124-33-4;ammonium diethylcarbamodithioate;ammoniumdiethylcarbamodithioate;SCHEMBL451162;AKOS025243468

Chemical Property of Ammonium diethylcarbamodithioate

Chemical Property:

• Melting Point: 80 °C (dec.)(lit.)
• Boiling Point: 176.4°Cat760mmHg
• Flash Point: 60.5°C
• PSA: 77.37000
• Density: 1.086g/cm³
• LogP: 1.86680
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 166.05984080
• Heavy Atom Count: 9
• Complexity: 73

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ammonium diethyldithiocarbamate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCN(CC)C(=S)[S-].[NH4+]
• Uses: Reactant involved in: ? ;Reactions with copper acetylacetonato complex1? ;Triazole compounds2? ;Causing accelerated degradation of methyl iodide3 Ammonium diethyldithiocarbamate is suitable for use in a study to detect vascular O2- production in intact aortic segments by lucigenin-enhanced chemiluminescence method.

Technology Process of Ammonium diethylcarbamodithioate

There total 1 articles about Ammonium diethylcarbamodithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + diethylamine (109-89-7) → ammonium salt of N-diethylamino dithiocarbamic acid (21124-33-4)

Guidance literature:

With ammonia;

Reference yield: 90.0%

Ditiocarb ammonium (21124-33-4) + molybdenum oxo-bis(dithiolene) → [Ph4P][Mo(IV)(Et2NCS2)(maleonitriledithiolate)2] (1180504-72-6)

Guidance literature:

With methanesulfonic acid; In dichloromethane; (ar); to soln. of molubdenium complex and (NH4)(Et2NCS2) in CH2Cl2 in cold was added methanesulfonic acid with stirring; precipitated with petroleum ether (60-80.degre.C), solid was dissolved in MeCN containing 2-aminothiophenol followed by addition of iPrOH and Et2O, kept overnight at 4°C, elem. anal.;

DOI:10.1016/j.ica.2009.03.036

Reference yield: 90.0%

Ditiocarb ammonium (21124-33-4) + [PPN][Mo(IV)O(maleonitriledithiolate)2] → [PPN][W(IV)(Et2NCS2)(maleonitriledithiolate)2] (1180665-09-1)

Guidance literature:

With methanesulfonic acid; In dichloromethane; (ar); to soln. of tungsten complex and (NH4)(Et2NCS2) in CH2Cl2 in cold was added methanesulfonic acid with stirring; precipitated with petroleum ether (60-80.degre.C), solid was dissolved in MeCN containing 2-aminothiophenol followed by addition of iPrOH and Et2O, kept overnight at 4°C, elem. anal.;

DOI:10.1016/j.ica.2009.03.036

upstream raw materials:

carbon disulfide

diethylamine

Downstream raw materials:

methyl diethyldithiocarbamate

ferric tri(N,N-diethyldithiocarbamate)

copper(II) bis(diethyldithiocarbamate)

[Ph₄P][Mo(IV)(Et₂NCS₂)(maleonitriledithiolate)2]

Refernces