N,N',N''-{Phosphanetriyltris[(4,1-phenylene)methylene]}tris(N-methylmethanamine)

Base Information

Chemical Name:N,N',N''-{Phosphanetriyltris[(4,1-phenylene)methylene]}tris(N-methylmethanamine)
CAS No.:78357-41-2
Molecular Formula:C27H36N3P
Molecular Weight:433.577
Hs Code.:
DSSTox Substance ID:DTXSID90570464
Nikkaji Number:J2.270.995J
Wikidata:Q82457920

Synonyms:78357-41-2;SCHEMBL8734956;DTXSID90570464;N,N',N''-{Phosphanetriyltris[(4,1-phenylene)methylene]}tris(N-methylmethanamine);1,1',1''-(Phosphinetriyltris(benzene-4,1-diyl))tris(N,N-dimethylmethanamine)

Suppliers and Price of N,N',N''-{Phosphanetriyltris[(4,1-phenylene)methylene]}tris(N-methylmethanamine)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of N,N',N''-{Phosphanetriyltris[(4,1-phenylene)methylene]}tris(N-methylmethanamine)

Chemical Property:

XLogP3:4.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:9
Exact Mass:433.26468516
Heavy Atom Count:31
Complexity:413

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CN(C)CC1=CC=C(C=C1)P(C2=CC=C(C=C2)CN(C)C)C3=CC=C(C=C3)CN(C)C

Technology Process of N,N',N''-{Phosphanetriyltris[(4,1-phenylene)methylene]}tris(N-methylmethanamine)

There total 2 articles about N,N',N''-{Phosphanetriyltris[(4,1-phenylene)methylene]}tris(N-methylmethanamine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: tri{4-[(dimethylamino)methyl]phenyl}phosphane oxide

: 78357-41-2
tri{4-[(dimethylamino)methyl]phenyl}phosphane

Guidance literature:: With trichlorosilane; triethylamine; In benzene; for 2h; Heating;
DOI:10.1016/j.jorganchem.2005.09.009

Reference yield:

: 6274-57-3
(4-bromobenzyl)dimethylamine

: 78357-41-2
tri{4-[(dimethylamino)methyl]phenyl}phosphane

Guidance literature:: Multi-step reaction with 2 steps

1.1: t-BuLi / diethyl ether; pentane / 0.75 h / -78 °C

1.2: PBr₃ / diethyl ether; pentane / 16 h / -78 - 20 °C

1.3: 71 percent / aq. H₂O₂ / tetrahydrofuran / 2 h / 20 °C

2.1: 96 percent / HSiCl₃; Et₃N / benzene / 2 h / Heating

With trichlorosilane; tert.-butyl lithium; triethylamine; In diethyl ether; pentane; benzene;
DOI:10.1016/j.jorganchem.2005.09.009

Reference yield: 99.0%

: 78357-41-2
tri{4-[(dimethylamino)methyl]phenyl}phosphane

: 12080-32-9
dichloro( 1,5-cyclooctadiene)platinum(ll)

: 877129-04-9,888501-53-9
cis-[PtCl₂(tri(4-[(dimethylamino)methyl]phenyl)phosphane)2]

Guidance literature:: In dichloromethane; (N2); std. Schlenk technique; soln. of Pt complex was added to soln. of ligand in CH2Cl2; mixt. was stirred at room temp. for 1 h; refluxed for 15 min; evapd.; washed (hexane); elem. anal.;
DOI:10.1016/j.jorganchem.2005.09.009