Mercury, [4-(dimethylamino)phenyl]hydroxy-

Base Information

• Chemical Name: Mercury, [4-(dimethylamino)phenyl]hydroxy-
• CAS No.: 79175-36-3
• Molecular Formula: C₈H₁₁HgNO
• Molecular Weight: 337.771
• Mol file: 79175-36-3.mol

Synonyms:

Chemical Property of Mercury, [4-(dimethylamino)phenyl]hydroxy-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mercury, [4-(dimethylamino)phenyl]hydroxy-

There total 2 articles about Mercury, [4-(dimethylamino)phenyl]hydroxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

p-dimethylaminophenylmercury acetate (23332-31-2) + sodium hydroxide (1310-73-2) → 4-dimethylaminophenylmercury hydroxide (79175-36-3)

Guidance literature:

In methanol; water; an aq. soln. of NaOH was added to a slurry of Hg-contg. compd. (5 mmol) in MeOH; the mixt. was heated under reflux for 30-60 min; after cooling, the complex was collected by filtration; the solid was recrystd. from boiling water; elem. anal.;

DOI:10.1016/j.jorganchem.2003.10.040

Reference yield:

N,N-dimethyl-aniline (121-69-7,77733-26-7) → 4-dimethylaminophenylmercury hydroxide (79175-36-3)

Guidance literature:

Multi-step reaction with 2 steps

1: ethanol

2: water; methanol

In methanol; ethanol; water;

DOI:10.1016/j.jorganchem.2003.10.040

Reference yield:

4-dimethylaminophenylmercury hydroxide (79175-36-3) → 4,4'-mercuriobis(N,N-dimethylaniline) (4219-76-5)

Guidance literature:

In acetone; a small amt. of Hg-contg. compd. was dissolved in hot acetone and the soln. was boiled; slow cooling to room temp.; elem. anal.;

DOI:10.1016/j.jorganchem.2003.10.040

upstream raw materials:

p-dimethylaminophenylmercury acetate

sodium hydroxide

N,N-dimethyl-aniline

Downstream raw materials:

4,4'-mercuriobis(N,N-dimethylaniline)

Refernces

Characterisation of the first authenticated organomercury hydroxide, 4-Me₂NC₆H₄HgOH

10.1016/j.jorganchem.2003.10.040

The study presents the synthesis and comprehensive characterization of 4-Me2NC6H4HgOH, the first verified organomercury hydroxide that crystallizes as discrete molecules in the solid state. The researchers detail its preparation from 4-Me2NC6H4HgOAc and discuss the structures of related compounds, including 4-Me2NC6H4HgOAc and (4-Me2NC6H4)2Hg. The study delves into the complex history of organomercury hydroxides, resolving previous conflicting reports and misconceptions about their existence and properties. It also explores the behavior of these compounds in aqueous solution, pointing to pH-dependent equilibria involving various species. The researchers used techniques such as electrospray mass spectrometry, nuclear magnetic resonance, infrared spectroscopy, and X-ray crystallography to characterize the compounds. The results provide a clear structural and spectral signature of 4-Me2NC6H4HgOH, confirming its status as a true organomercury hydroxide and contributing to a better understanding of arylmercury chemistry.