[4-(dimethylamino)phenyl]mercury acetate

Base Information

• Chemical Name: [4-(dimethylamino)phenyl]mercury acetate
• CAS No.: 23332-31-2
• Molecular Formula: C10H13 Hg N O2
• Molecular Weight: 379.809
• Mol file: 23332-31-2.mol

Synonyms:Aniline,p-(acetoxymercuri)-N,N-dimethyl- (6CI,7CI); Mercury,(acetato)[p-(dimethylamino)phenyl]- (8CI); Mercury,(acetato-O)[4-(dimethylamino)phenyl]-; 4-(Dimethylamino)phenylmercury acetate;Acetato[4-(dimethylamino)phenyl]mercury; p-(Dimethylamino)phenylmercuricacetate

Chemical Property of [4-(dimethylamino)phenyl]mercury acetate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 43.37000
• Density: g/cm³
• LogP: 0.11480

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [4-(dimethylamino)phenyl]mercury acetate

There total 2 articles about [4-(dimethylamino)phenyl]mercury acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

mercury(II) diacetate (1600-27-7) + N,N-dimethyl-aniline (121-69-7,77733-26-7) → (p-(dimethylamino)phenyl)mercuric acetate (23332-31-2)

Guidance literature:

In ethanol; water; to Hg(O-Ac)2 in 50% ethanol added N,N-dimethylaniline in 96% ethanol;

DOI:10.1021/ja00402a017

Reference yield: 75.0%

mercury(II) diacetate (1600-27-7) + N,N-dimethyl-aniline (121-69-7,77733-26-7) → p-dimethylaminophenylmercury acetate (23332-31-2)

Guidance literature:

In ethanol; N,N-dimethylaniline (0.100 mol) was added to a stirred slurry of Hg-contg. compd. (0.100 mol) in EtOH at room temp.; the mixt. was stirred overnight (24 h); the complex was collected by filtration and recrystd. from hot acetone; the supernatant was concd. and stored at -20°C; elem. anal.;

DOI:10.1016/j.jorganchem.2003.10.040

Reference yield: 99.0%

p-dimethylaminophenylmercury acetate (23332-31-2) + lithium chloride → (p-(CH3)2N-C6H4)HgCl (23000-67-1)

Guidance literature:

In water; acetone; Hg-contg. compd. was dissolved in hot acetone and treated with excess ofsatd. aq. soln. of LiCl; stirring for a few minutes; the complex was collected by filtration and air-dried; elem. anal.;

DOI:10.1016/j.jorganchem.2003.10.040

upstream raw materials:

mercury(II) diacetate

N,N-dimethyl-aniline

Downstream raw materials:

bis(p-dimethylaminophenyl)methanone

N,N,N',N'-tetramethylbenzidine

4-(dimethylamino)phenyl phenyl telluride

(4-Bromphenyl)<4-(dimethylamino)phenyl>tellur

Refernces

• 1、 Seyferth, Dietmar,Nestle, Mara Ozolins. "Organocobalt Cluster Complexes. 23. Novel Chemistry of (Acylmethylidyne)- and (Aroylmethylidyne)tricobalt Nonacarbonyl Complexes". . p. 3320 - 3328. Retrieved 2007/10/02.