Silane, [(2,6-dimethyl-1,5-cyclohexadien-1-yl)oxy]trimethyl-

Base Information

Chemical Name:Silane, [(2,6-dimethyl-1,5-cyclohexadien-1-yl)oxy]trimethyl-
CAS No.:83022-81-5
Molecular Formula:C11H20OSi
Molecular Weight:196.365
Hs Code.:
DSSTox Substance ID:DTXSID30461584
Nikkaji Number:J1.892.961I
Wikidata:Q82285954

Synonyms:83022-81-5;Silane, [(2,6-dimethyl-1,5-cyclohexadien-1-yl)oxy]trimethyl-;DTXSID30461584

Suppliers and Price of Silane, [(2,6-dimethyl-1,5-cyclohexadien-1-yl)oxy]trimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Silane, [(2,6-dimethyl-1,5-cyclohexadien-1-yl)oxy]trimethyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:196.128341792
Heavy Atom Count:13
Complexity:256

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=C(C(=CCC1)C)O[Si](C)(C)C

Technology Process of Silane, [(2,6-dimethyl-1,5-cyclohexadien-1-yl)oxy]trimethyl-

There total 2 articles about Silane, [(2,6-dimethyl-1,5-cyclohexadien-1-yl)oxy]trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 75-77-4
chloro-trimethyl-silane

: 40790-56-5
2,6-dimethyl-2-cyclohexen-1-one

: 83022-81-5
1-(trimethylsiloxy)-2,6-dimethylcyclohexa-1,5-diene

Guidance literature:: 2,6-dimethyl-2-cyclohexen-1-one; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h;

chloro-trimethyl-silane; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 0.75h;
DOI:10.1021/ol034217k

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 40790-56-5
2,6-dimethyl-2-cyclohexen-1-one

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 83022-81-5
1-(trimethylsiloxy)-2,6-dimethylcyclohexa-1,5-diene

: (1S,2R,4R)-4,6-Dimethyl-5-trimethylsilanyloxy-bicyclo[2.2.2]oct-5-ene-2-carboxylic acid methyl ester

: 137762-21-1
(1S,6S,8R,11S)-2,6-Dimethyl-9-oxo-10-oxa-tricyclo[6.2.2.0^1,6]dodec-2-ene-11-carboxylic acid methyl ester

Guidance literature:: With lithium diisopropyl amide; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, -78 deg C, 1 h;
DOI:10.1016/0040-4039(91)80076-I

Reference yield: 70.0%

: 7572-29-4
dichloroethyne

: 83022-81-5
1-(trimethylsiloxy)-2,6-dimethylcyclohexa-1,5-diene

: 73843-29-5
6-(chloroethynyl)-2,6-dimethyl-2-cyclohexen-1-one

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide; In tetrahydrofuran; for 4h; from -78 deg C to room temp.;
DOI:10.1021/ja00324a025