Tris(tert-butoxy)vinylsilane

Base Information

• Chemical Name: Tris(tert-butoxy)vinylsilane
• CAS No.: 5356-88-7
• Molecular Formula: C14H30 O3 Si
• Molecular Weight: 274.476
• European Community (EC) Number: 226-343-8
• DSSTox Substance ID: DTXSID90968327
• Nikkaji Number: J1.865.163G
• Wikidata: Q72515395
• Mol file: 5356-88-7.mol

Synonyms:VINYLTRI-T-BUTOXYSILANE;5356-88-7;Tris(tert-butoxy)vinylsilane;Silyl peroxide;ethenyl-tris[(2-methylpropan-2-yl)oxy]silane;Y-5712 silyl peroxide;Silane, tri-tert-butoxyvinyl-;EINECS 226-343-8;Tris(1,1-dimethylethoxy)ethenylsilane;BRN 2210775;Silane, tris(1,1-dimethylethoxy)ethenyl-;Y 5712;tri-tert-butoxy(vinyl)silane;VINYL TRIS-TERT-BUTOXYSILANE;vinyltri-tert-butoxysilane;SCHEMBL81570;vinyl tris(tert-butoxy)silane;Tri-tert-butoxy(ethenyl)silane;tris(tert-butoxy)(ethenyl)silane;DTXSID90968327;MFCD00054894;LS-145408

Chemical Property of Tris(tert-butoxy)vinylsilane

Chemical Property:

• Boiling Point: 266.5 °C at 760 mmHg
• Flash Point: 114.9 °C
• PSA: 27.69000
• Density: 0,869 g/cm³
• LogP: 4.09580
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 7
• Exact Mass: 274.19642135
• Heavy Atom Count: 18
• Complexity: 238

Purity/Quality:

98%,99%, ^*data from raw suppliers

VINYLTRI-TERT-BUTOXYSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)O[Si](C=C)(OC(C)(C)C)OC(C)(C)C

Technology Process of Tris(tert-butoxy)vinylsilane

There total 3 articles about Tris(tert-butoxy)vinylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

trichlorovinylsilane (75-94-5) + potassium tert-butylate (865-47-4) → tris(tert-butoxy)(vinyl)silane (5356-88-7)

Guidance literature:

In hexane; at 20 ℃; for 24h;

DOI:10.1002/ejic.201601341

Reference yield: 70.0%

trichlorovinylsilane (75-94-5) + tert-butyl alcohol (75-65-0) → tris(tert-butoxy)(vinyl)silane (5356-88-7)

Guidance literature:

With urea;

Reference yield:

→ tris(tert-butoxy)(vinyl)silane (5356-88-7)

Guidance literature:

aus Vinyltrichlorsilan;

upstream raw materials:

trichlorovinylsilane

tert-butyl alcohol

potassium tert-butylate

Downstream raw materials:

C₂₉H₄₇NO₇S₂Si

Refernces

• 1、 Voronkov, M. G.,Sorokin, M. S.. "PHOTOCHEMICAL ADDITION OF ALKANETHIOLS TO ALKENYLTRIALKOXYSILANES AND 1-(ALKENYL)SILATRANES". . p. 1803 - 1806. Retrieved 2007/10/02.