1-CHLORO-1-METHYLSILACYCLOBUTANE

Base Information

Chemical Name:1-CHLORO-1-METHYLSILACYCLOBUTANE
CAS No.:2351-34-0
Molecular Formula:C4H9 Cl Si
Molecular Weight:120.654
Hs Code.:
Mol file:2351-34-0.mol

Synonyms:1-Chloro-1-methyl-1-silacyclobutane;1-Chloro-1-methylsilacyclobutane; 1-Methyl-1-chloro-1-silacyclobutane;1-Methyl-1-chlorosilacyclobutane

Suppliers and Price of 1-CHLORO-1-METHYLSILACYCLOBUTANE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
1-Chloro-1-methylsilacyclobutane 98%
5g
$ 234.00

Matrix Scientific
1-Chloro-1-methylsiletane 95+%
1g
$ 588.00

Matrix Scientific
1-Chloro-1-methylsiletane 95+%
250mg
$ 265.00

Total 24 raw suppliers

Chemical Property of 1-CHLORO-1-METHYLSILACYCLOBUTANE

Chemical Property:

Vapor Pressure:44mmHg at 25°C
Refractive Index:n20/D 1.45(lit.)
Boiling Point:99.4°Cat760mmHg
Flash Point:2.6°C
PSA：0.00000
Density:0.98g/cm³
LogP:2.20420
Solubility.:soluble in most aprotic organic solvents.

Purity/Quality:

99.5% ^*data from raw suppliers

1-Chloro-1-methylsilacyclobutane 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,C
Statements: 11-14-34
Safety Statements: 16-26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Physical properties bp 103°C; d 0.985 g cm?3.
Uses Siletanes (silacyclobutanes) represent a unique class of silicon-based reagents that have enjoyed much success in a number of synthetic applications including aldol reactions, allylations, cross-coupling reactions, carbosilane oxidations, and ring expansions. The manifestation of their strain in enhanced Lewis acidity and in the ring opening to silanols accounts for their utility. 1-Chloro-1-methylsiletane can be used for the preparation of the various siletane derivatives for these applications.Grignard reagents react efficiently with 1-chloro-1-methylsiletane to provide the corresponding aryl-, alkenyl-, or alkylsiletanes (eqs 1–3).On the contrary, reactions with alkyllithiums are limited to the reaction of 1 with a lithium acetylide (eq 4).The reaction of 1 with an intermediate vinylalane obtained by hydroalumination of 1-heptyne gave (E)-1-heptenylmethylsiletane in >99/1 isomeric purity (eq 5).The reaction of 1 with LiAlD4 afforded 1-deuterio-1-methylsiletane (eq 6). Intermediate in the formation of enoxysilacyclobutanes.

Technology Process of 1-CHLORO-1-METHYLSILACYCLOBUTANE

There total 6 articles about 1-CHLORO-1-METHYLSILACYCLOBUTANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%