a-L-Arabinopyranoside, (3b,16b,23R)-16,23:16,30-diepoxy-20-hydroxydammar-24-en-3-ylO-6-deoxy-b-D-glucopyranosyl-(1®2)-O-[b-D-glucopyranosyl-(1®3)]- (9CI)

Base Information

• Chemical Name: a-L-Arabinopyranoside, (3b,16b,23R)-16,23:16,30-diepoxy-20-hydroxydammar-24-en-3-ylO-6-deoxy-b-D-glucopyranosyl-(1®2)-O-[b-D-glucopyranosyl-(1®3)]- (9CI)
• CAS No.: 146503-30-2
• Molecular Formula: C₄₇H₇₆O₁₇
• Molecular Weight: 913.11
• Mol file: 146503-30-2.mol

Synonyms:4a,6a-Methano-1H,6H-phenanthro[2,1-d]pyrano[2,3-b]pyran,a-L-arabinopyranoside deriv.;Dammarane, a-L-arabinopyranoside deriv.;(-)-Hoduloside III; Hoduloside III

Chemical Property of a-L-Arabinopyranoside, (3b,16b,23R)-16,23:16,30-diepoxy-20-hydroxydammar-24-en-3-ylO-6-deoxy-b-D-glucopyranosyl-(1®2)-O-[b-D-glucopyranosyl-(1®3)]- (9CI)

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of a-L-Arabinopyranoside, (3b,16b,23R)-16,23:16,30-diepoxy-20-hydroxydammar-24-en-3-ylO-6-deoxy-b-D-glucopyranosyl-(1®2)-O-[b-D-glucopyranosyl-(1®3)]- (9CI)

There total 2 articles about a-L-Arabinopyranoside, (3b,16b,23R)-16,23:16,30-diepoxy-20-hydroxydammar-24-en-3-ylO-6-deoxy-b-D-glucopyranosyl-(1®2)-O-[b-D-glucopyranosyl-(1®3)]- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

jujuboside B (Compound I) (55466-05-2,68144-21-8,77943-54-5) → D-Xylose (87-72-9,608-45-7,608-46-8,608-47-9,2460-44-8,6748-95-4,6763-34-4,7261-26-9,7283-06-9,7283-07-0,7296-55-1,7296-56-2,7296-58-4,7296-59-5,7296-60-8,7296-61-9,7296-62-0,7322-30-7,10257-31-5,10257-32-6,10257-33-7,10257-34-8,10257-35-9,19982-83-3,20242-88-0,28697-53-2,36562-42-2,41546-41-2,89299-64-9,107655-34-5,115794-06-4,115794-07-5,130550-15-1,130606-21-2) + 3-O-<α-L-Rhamnopyranosyl-(1->2)-<β-D-glucopyranosyl-(1->3)>-α-L-arabinopyranosyl>jujubogenin (77174-32-4,77943-56-7,77943-83-0,146503-30-2)

Guidance literature:

With hesperidinase; Tween 80; In ethanol; water; at 37 ℃; for 72h;

DOI:10.1248/cpb.29.676

Reference yield:

Zizyphus saponin III (55466-05-2,68144-21-8,77943-54-5) → D-Xylose (87-72-9,608-45-7,608-46-8,608-47-9,2460-44-8,6748-95-4,6763-34-4,7261-26-9,7283-06-9,7283-07-0,7296-55-1,7296-56-2,7296-58-4,7296-59-5,7296-60-8,7296-61-9,7296-62-0,7322-30-7,10257-31-5,10257-32-6,10257-33-7,10257-34-8,10257-35-9,19982-83-3,20242-88-0,28697-53-2,36562-42-2,41546-41-2,89299-64-9,107655-34-5,115794-06-4,115794-07-5,130550-15-1,130606-21-2) + Zizyphus saponin I (77174-32-4,77943-56-7,77943-83-0,146503-30-2)

Guidance literature:

With hesperidinase; In water; at 37 ℃; for 96h;

DOI:10.1248/cpb.29.676

Reference yield:

Zizyphus saponin I (77174-32-4,77943-56-7,77943-83-0,146503-30-2) → D-Glucose (2280-44-6) + ebelin lactone (3649-76-1) + L-(+)-arabinose (87-72-9,608-45-7,608-46-8,608-47-9,2460-44-8,6748-95-4,6763-34-4,7261-26-9,7283-06-9,7283-07-0,7296-55-1,7296-56-2,7296-58-4,7296-59-5,7296-60-8,7296-61-9,7296-62-0,7322-30-7,10257-31-5,10257-32-6,10257-33-7,10257-34-8,10257-35-9,19982-83-3,20242-88-0,28697-53-2,36562-42-2,41546-41-2,89299-64-9,107655-34-5,115794-06-4,115794-07-5,130550-15-1,130606-21-2) + 6-deoxy-L-talopyranoe (73-34-7,87-96-7,488-79-9,551-63-3,609-01-8,643-17-4,643-18-5,4164-09-4,6014-42-2,6155-36-8,6189-71-5,6696-41-9,6736-43-2,13224-93-6,22611-09-2,28161-49-1,28161-50-4,28161-52-6,45864-36-6,63814-64-2,71116-59-1,71116-61-5,72598-05-1,87936-88-7,87936-89-8,97466-79-0,116908-82-8,120442-60-6,123484-22-0,133576-32-6)

Guidance literature:

With sulfuric acid; In ethanol; for 2h; Yield given. Yields of byproduct given; Heating;

DOI:10.1248/cpb.29.676

upstream raw materials:

Zizyphus saponin III

jujuboside B (Compound I)

Downstream raw materials:

D-Glucose

ebelin lactone

L-(+)-arabinose

6-deoxy-L-talopyranoe