Ruthenium, eta5-pentamethylcyclopentadienyl-eta5-1,2,3,3a,7a-indenyl)-

Base Information

Chemical Name:Ruthenium, eta5-pentamethylcyclopentadienyl-eta5-1,2,3,3a,7a-indenyl)-
CAS No.:115560-11-7
Molecular Formula:C19H22 Ru
Molecular Weight:348.43
Hs Code.:

Synonyms:Ruthenium, .eta.5-pentamethylcyclopentadienyl-.eta.5-1,2,3,3a,7a-indenyl)-

Suppliers and Price of Ruthenium, eta5-pentamethylcyclopentadienyl-eta5-1,2,3,3a,7a-indenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Ruthenium, eta5-pentamethylcyclopentadienyl-eta5-1,2,3,3a,7a-indenyl)-

Chemical Property:

Vapor Pressure:1.97mmHg at 25°C
Boiling Point:170.2°Cat760mmHg
Flash Point:44.4°C
PSA：0.00000
Density:g/cm³
LogP:5.15510
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:0
Exact Mass:352.076491
Heavy Atom Count:20
Complexity:369

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[C-]1C(=C(C(=C1C)C)C)C.[CH-]1[CH-][C-]2C=CC=C[C-]2[CH-]1.[Ru]

Technology Process of Ruthenium, eta5-pentamethylcyclopentadienyl-eta5-1,2,3,3a,7a-indenyl)-

There total 4 articles about Ruthenium, eta5-pentamethylcyclopentadienyl-eta5-1,2,3,3a,7a-indenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 96503-27-4
pentamethylcyclopentadienylruthenium dichloride

: 23181-84-2
sodium indenyl

: 115560-11-7
Cp*Ru(η⁵-indenyl)

Guidance literature:: In tetrahydrofuran; heating (60°C, 72 h), solvent removal (red. press.), residue extd. (toluene), volatiles removal (red. pressure), residue extd. (light petroleum, b.p. 40-60°C); chromy. (alumina), elution (light petroleum); collection of bright yellow band, concn. (red. pressure), cooling (-80°C, 24 h) on crystn., drying (vac.); elem. anal.;

Reference yield: 70.0%

: tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate

: 20669-47-0
indenyllithium

: 115560-11-7
Cp*Ru(η⁵-indenyl)

Guidance literature:: In tetrahydrofuran; under argon;
DOI:10.1016/0022-328X(91)86434-R

Reference yield: 59.0%

: 96503-27-4
pentamethylcyclopentadienylruthenium dichloride

: 917-54-4
methyllithium

: 95-13-6
1-indene

: 115560-11-7
Cp*Ru(η⁵-indenyl)

Guidance literature:: In tetrahydrofuran; diethyl ether; (N2); to indene in THF was added MeLi in ether and stirred for 1 h, Ru complex was added and refluxed for 4 h, solvents were removed in vac.; residue was extd. with hot hexane, soln. passed through alumina, bright yellow fraction was collected, solvent was removed under reduced pressure; elem. anal.;
DOI:10.1021/ja00226a030