Benzoyl chloride 4-nitrophenylhydrazone

Base Information

• Chemical Name: Benzoyl chloride 4-nitrophenylhydrazone
• CAS No.: 25939-13-3
• Molecular Formula: C13H10 Cl N3 O2
• Molecular Weight: 275.694
• Hs Code.: 2928000090
• ChEMBL ID: CHEMBL150400
• Mol file: 25939-13-3.mol

Synonyms:Benzoyl chloride 4-nitrophenylhydrazone;25939-13-3;NSC 140248;BRN 0753302;(Z)-N-(4-nitrophenyl)benzenecarbohydrazonoyl chloride;BENZOYL CHLORIDE, (p-NITROPHENYL)HYDRAZONE;N-(4-Nitrophenyl)benzenecarbohydrazonoyl chloride;4-15-00-00360 (Beilstein Handbook Reference);CHEMBL150400;LS-42609;N-(4-Nitrophenyl)benzenecarbohydrazonoylchloride;N-[(4-nitrophenyl)amino]-benzenecarboximidoyl chloride

Chemical Property of Benzoyl chloride 4-nitrophenylhydrazone

Chemical Property:

• Vapor Pressure: 2.2E-07mmHg at 25°C
• Melting Point: 191-191.5 °C
• Boiling Point: 423.6°Cat760mmHg
• PKA: 13.73±0.10(Predicted)
• Flash Point: 210°C
• PSA: 70.21000
• Density: 1.31g/cm³
• LogP: 4.20350
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 275.0461543
• Heavy Atom Count: 19
• Complexity: 329

Purity/Quality:

97% ^*data from raw suppliers

N-(4-Nitrophenyl)benzenecarbohydrazonoylchloride 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=NNC2=CC=C(C=C2)[N+](=O)[O-])Cl
• Isomeric SMILES: C1=CC=C(C=C1)/C(=N/NC2=CC=C(C=C2)[N+](=O)[O-])/Cl

Technology Process of Benzoyl chloride 4-nitrophenylhydrazone

There total 6 articles about Benzoyl chloride 4-nitrophenylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

1-benzoyl-2-(p-nitrophenyl)hydrazine (1088-95-5) → N-(p-nitrophenyl)benzohydrazonoyl chloride (25939-13-3)

Guidance literature:

With phosphorus pentachloride;

DOI:10.1016/S0040-4020(01)85755-0

Reference yield: 73.0%

anti-benzaldehyde (4'-nitrophenyl)hydrazone (33786-33-3) → N-(p-nitrophenyl)benzohydrazonoyl chloride (25939-13-3)

Guidance literature:

With N-chlorosuccinimide-dimethyl sulfide; In dichloromethane; at -40 ℃;

DOI:10.1016/0040-4020(95)00916-7

Reference yield: 45.0%

→ N-(p-nitrophenyl)benzohydrazonoyl chloride (25939-13-3)

Guidance literature:

With tetrachloromethane; triphenylphosphine; In acetonitrile; at 20 ℃; Inert atmosphere;

upstream raw materials:

phenyldiazomethane

4-nitrobenzenediazonium chloride

1-benzoyl-2-(p-nitrophenyl)hydrazine

anti-benzaldehyde (4'-nitrophenyl)hydrazone

Downstream raw materials:

1-(4-nitro-phenyl)-3-phenyl-(3ar,6ac)-3a,4,5,6a-tetrahydro-1H-furo[2,3-c]pyrazole

C₁₅H₁₆N₄O₂

4-ethoxy-1-(4-nitro-phenyl)-3-phenyl-1,4,5,6-tetrahydro-[1,2,4]diazaphosphinine 4-oxide

4-ethoxy-5-methyl-1-(4-nitro-phenyl)-3-phenyl-1,4,5,6-tetrahydro-[1,2,4]diazaphosphinine 4-oxide