Phosphoric acid, (6R,12S)-6,12-bis[(4-methoxyphenyl)methoxy]-2,2-dimethyl-9-oxido-3,3 -diphenyl-9-(phenylmethoxy)-4,8,10-trioxa-9-phospha-3-silatridec-13-yl (2S)-2,3-bis(phenylmethoxy)propyl phenylmethyl ester

Base Information

Chemical Name:Phosphoric acid, (6R,12S)-6,12-bis[(4-methoxyphenyl)methoxy]-2,2-dimethyl-9-oxido-3,3 -diphenyl-9-(phenylmethoxy)-4,8,10-trioxa-9-phospha-3-silatridec-13-yl (2S)-2,3-bis(phenylmethoxy)propyl phenylmethyl ester
CAS No.:849240-71-7
Molecular Formula:C69H80O15P2Si
Molecular Weight:1239.42
Hs Code.:

Phosphoric acid,
(6R,12S)-6,12-bis[(4-methoxyphenyl)methoxy]-2,2-dimethyl-9-oxido-3,3
-diphenyl-9-(phenylmethoxy)-4,8,10-trioxa-9-phospha-3-silatridec-13-yl
(2S)-2,3-bis(phenylmethoxy)propyl phenylmethyl ester

Synonyms:

Suppliers and Price of Phosphoric acid, (6R,12S)-6,12-bis[(4-methoxyphenyl)methoxy]-2,2-dimethyl-9-oxido-3,3 -diphenyl-9-(phenylmethoxy)-4,8,10-trioxa-9-phospha-3-silatridec-13-yl (2S)-2,3-bis(phenylmethoxy)propyl phenylmethyl ester

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Chemical Property of Phosphoric acid, (6R,12S)-6,12-bis[(4-methoxyphenyl)methoxy]-2,2-dimethyl-9-oxido-3,3 -diphenyl-9-(phenylmethoxy)-4,8,10-trioxa-9-phospha-3-silatridec-13-yl (2S)-2,3-bis(phenylmethoxy)propyl phenylmethyl ester

Chemical Property:

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Useful:

Technology Process of Phosphoric acid, (6R,12S)-6,12-bis[(4-methoxyphenyl)methoxy]-2,2-dimethyl-9-oxido-3,3 -diphenyl-9-(phenylmethoxy)-4,8,10-trioxa-9-phospha-3-silatridec-13-yl (2S)-2,3-bis(phenylmethoxy)propyl phenylmethyl ester

There total 9 articles about Phosphoric acid, (6R,12S)-6,12-bis[(4-methoxyphenyl)methoxy]-2,2-dimethyl-9-oxido-3,3 -diphenyl-9-(phenylmethoxy)-4,8,10-trioxa-9-phospha-3-silatridec-13-yl (2S)-2,3-bis(phenylmethoxy)propyl phenylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Phosphoric acid benzyl ester (R)-3-{benzyloxy-[(R)-3-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-propoxy]-phosphanyloxy}-2-(4-methoxy-benzyloxy)-propyl ester (S)-2,3-bis-benzyloxy-propyl ester

: 849240-71-7
Phosphoric acid benzyl ester (S)-3-{benzyloxy-[(R)-3-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-propoxy]-phosphoryloxy}-2-(4-methoxy-benzyloxy)-propyl ester (S)-2,3-bis-benzyloxy-propyl ester

Guidance literature:: With tert.-butylhydroperoxide;
DOI:10.1002/anie.200390243

Reference yield:

: 849240-70-6
benzyl [(2S)-1,2-di-benzyloxy-propan-3-yl] [(2R)-1-hydroxy-2-(4-methoxybenzyloxy)propan-3-yl] phosphate

: 849240-71-7
Phosphoric acid benzyl ester (S)-3-{benzyloxy-[(R)-3-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-propoxy]-phosphoryloxy}-2-(4-methoxy-benzyloxy)-propyl ester (S)-2,3-bis-benzyloxy-propyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: tetrazole / CH₂Cl₂ / 1.5 h / 20 °C

2: 3.1 g / tert-butyl hydroperoxide / CH₂Cl₂; decane

With 1H-tetrazole; tert.-butylhydroperoxide; In decane; dichloromethane;
DOI:10.1016/j.tetasy.2004.11.070

Reference yield:

: Phosphorous acid benzyl ester (S)-2,3-bis-benzyloxy-propyl ester (R)-3-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-propyl ester

: 849240-71-7
Phosphoric acid benzyl ester (S)-3-{benzyloxy-[(R)-3-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-propoxy]-phosphoryloxy}-2-(4-methoxy-benzyloxy)-propyl ester (S)-2,3-bis-benzyloxy-propyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 3.5 g / tert-butyl hydroperoxide / CH₂Cl₂; decane

2: 87 percent / tetrabutylammonium fluoride / tetrahydrofuran / 20 °C

3: tetrazole / CH₂Cl₂ / 1.5 h / 20 °C

4: 3.1 g / tert-butyl hydroperoxide / CH₂Cl₂; decane

With 1H-tetrazole; tert.-butylhydroperoxide; tetrabutyl ammonium fluoride; In tetrahydrofuran; decane; dichloromethane;
DOI:10.1016/j.tetasy.2004.11.070