Technology Process of Tributylpentylstannane
There total 7 articles about Tributylpentylstannane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
zinc;
In
tetrahydrofuran; water;
under air atm., at room temp., cosolvent media: H2O(NH4Cl)/THF/Zn, alkyliodide was added dropwise to the alkyl tin halide in solvent mixt. over 15 min, reaction time: 5.0 h, after 1.5 h a further addition of alkyl i odide was carried out; Zn was filtered off, aq. phase was extd. three times with n-pentane, organic phase was washed with sat. aq. NaCl and dried over MgSO4, solvent was removed, crude oil was distilled under vac., then chromd. using n-hexane; (119Sn NMR monitoring);
DOI:10.1016/S0022-328X(00)00388-0
- Guidance literature:
-
With
zinc;
In
tetrahydrofuran; water;
under air atm., at room temp., cosolvent media: H2O(NH4Cl)/THF/Zn, alkyliodide was added dropwise to the alkyl tin halide in solvent mixt. over 15 min, reaction time: 4.5 h; Zn was filtered off, aq. phase was extd. three times with n-pentane, organic phase was washed with sat. aq. NaCl and dried over MgSO4, solvent was removed, crude oil was distilled under vac., then chromd. using n-hexane; (119Sn NMR monitoring);
DOI:10.1016/S0022-328X(00)00388-0
- Guidance literature:
-
With
Zn; NH4Cl;
In
tetrahydrofuran; water;
DOI:10.1021/om9507742
