1,3-Dioxane-4-acetic acid, 6-[(1R,3R)-5-(dimethoxyphosphinyl)-1-[2-[[(1,1-dimethylethyl)diphenylsil yl]oxy]ethyl]-3-methyl-4-oxopentyl]-2,2,5-trimethyl-, (4R,5S,6S)-

Base Information

Chemical Name:1,3-Dioxane-4-acetic acid, 6-[(1R,3R)-5-(dimethoxyphosphinyl)-1-[2-[[(1,1-dimethylethyl)diphenylsil yl]oxy]ethyl]-3-methyl-4-oxopentyl]-2,2,5-trimethyl-, (4R,5S,6S)-
CAS No.:849418-89-9
Molecular Formula:C35H53O9PSi
Molecular Weight:676.86
Hs Code.:

1,3-Dioxane-4-acetic acid,
6-[(1R,3R)-5-(dimethoxyphosphinyl)-1-[2-[[(1,1-dimethylethyl)diphenylsil
yl]oxy]ethyl]-3-methyl-4-oxopentyl]-2,2,5-trimethyl-, (4R,5S,6S)-

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Chemical Property of 1,3-Dioxane-4-acetic acid, 6-[(1R,3R)-5-(dimethoxyphosphinyl)-1-[2-[[(1,1-dimethylethyl)diphenylsil yl]oxy]ethyl]-3-methyl-4-oxopentyl]-2,2,5-trimethyl-, (4R,5S,6S)-

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Technology Process of 1,3-Dioxane-4-acetic acid, 6-[(1R,3R)-5-(dimethoxyphosphinyl)-1-[2-[[(1,1-dimethylethyl)diphenylsil yl]oxy]ethyl]-3-methyl-4-oxopentyl]-2,2,5-trimethyl-, (4R,5S,6S)-

There total 4 articles about 1,3-Dioxane-4-acetic acid, 6-[(1R,3R)-5-(dimethoxyphosphinyl)-1-[2-[[(1,1-dimethylethyl)diphenylsil yl]oxy]ethyl]-3-methyl-4-oxopentyl]-2,2,5-trimethyl-, (4R,5S,6S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 849418-93-5
(3R,4S,5S,6R,8R)-10-dimethoxyphosphono-6-{2-(tert-butyldiphenylsilyloxy)ethyl}-3,5-isopropylidenedioxy-3,8-dimethyl-9-oxodecanal

: 849418-89-9
(3R,4S,5S,6R,8R)-10-dimethoxyphosphono-6-{2-(tert-butyldiphenylsilyloxy)ethyl}-3,5-isopropylidenedioxy-3,8-dimethyl-9-oxodecanoic acid

Guidance literature:: With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; In water; tert-butyl alcohol; at 20 ℃; for 0.166667h;
DOI:10.3987/COM-04-S(P)30

Reference yield:

: 113918-79-9
dimethyl (3R,5R,6S,7S,8R)-5-<2-(3,4-dimethoxybenzyloxy)ethyl>-3,7-dimethyl-6,8-isopropylidenedioxy-2-oxo-10-undecenylphosphonate

: 849418-89-9
(3R,4S,5S,6R,8R)-10-dimethoxyphosphono-6-{2-(tert-butyldiphenylsilyloxy)ethyl}-3,5-isopropylidenedioxy-3,8-dimethyl-9-oxodecanoic acid

Guidance literature:: Multi-step reaction with 4 steps

1.1: 80 percent / DDQ / CH₂Cl₂; H₂O / 1 h

2.1: 90 percent / imidazole / CH₂Cl₂ / 0.5 h / 20 °C

3.1: NMO; OsO₄ / acetone; H₂O; 2-methyl-propan-2-ol / 21 h / 20 °C

3.2: 83 percent / NaIO₄ / acetone; H₂O; 2-methyl-propan-2-ol / 0.5 h / 20 °C

4.1: 100 percent / 2-methyl-2-butene; NaH₂PO₄; NaClO₂ / 2-methyl-propan-2-ol; H₂O / 0.17 h / 20 °C

With 1H-imidazole; sodium chlorite; sodium dihydrogenphosphate; osmium(VIII) oxide; N-methyl-2-indolinone; 2-methyl-but-2-ene; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; acetone; tert-butyl alcohol;
DOI:10.3987/COM-04-S(P)30

Reference yield:

: 849418-91-3
dimethyl (3R,5R,6S,7S,8R)-5-(2-hydroxyethyl)-6,8-isopropylidenedioxy-3,7-dimethyl-2-oxo-10-undecenylphosphonate

: 849418-89-9
(3R,4S,5S,6R,8R)-10-dimethoxyphosphono-6-{2-(tert-butyldiphenylsilyloxy)ethyl}-3,5-isopropylidenedioxy-3,8-dimethyl-9-oxodecanoic acid

Guidance literature:: Multi-step reaction with 3 steps

1.1: 90 percent / imidazole / CH₂Cl₂ / 0.5 h / 20 °C

2.1: NMO; OsO₄ / acetone; H₂O; 2-methyl-propan-2-ol / 21 h / 20 °C

2.2: 83 percent / NaIO₄ / acetone; H₂O; 2-methyl-propan-2-ol / 0.5 h / 20 °C

3.1: 100 percent / 2-methyl-2-butene; NaH₂PO₄; NaClO₂ / 2-methyl-propan-2-ol; H₂O / 0.17 h / 20 °C

With 1H-imidazole; sodium chlorite; sodium dihydrogenphosphate; osmium(VIII) oxide; N-methyl-2-indolinone; 2-methyl-but-2-ene; In dichloromethane; water; acetone; tert-butyl alcohol;
DOI:10.3987/COM-04-S(P)30