Benzaldehyde, 2-[(methoxymethyl)thio]-

Base Information

• Chemical Name: Benzaldehyde, 2-[(methoxymethyl)thio]-
• CAS No.: 850306-53-5
• Molecular Formula: C9H10O2S
• Molecular Weight: 182.243
• Mol file: 850306-53-5.mol

Synonyms:

Chemical Property of Benzaldehyde, 2-[(methoxymethyl)thio]-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzaldehyde, 2-[(methoxymethyl)thio]-

There total 1 articles about Benzaldehyde, 2-[(methoxymethyl)thio]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1-bromo-2-<(methoxymethyl)thio>benzene (146335-10-6) → 2-methoxymethylsulfanyl-benzaldehyde (850306-53-5)

Guidance literature:

1-bromo-2-<(methoxymethyl)thio>benzene; With n-butyllithium; In tetrahydrofuran;

formaldehyd; In tetrahydrofuran;

DOI:10.1002/(SICI)1096-9063(199905)55:5<576::AID-PS953>3.0.CO;2-T

Reference yield: 100.0%

2-methoxymethylsulfanyl-benzaldehyde (850306-53-5) + trimethyl orthoformate (149-73-5) → 1-dimethoxymethyl-2-methoxymethylsulfanyl-benzene (850306-60-4)

Guidance literature:

With methanol; toluene-4-sulfonic acid; In benzene; at 20 ℃; for 0.166667h;

DOI:10.1055/s-2005-862379

Reference yield: 54.0%

6-methylhept-5-en-2-ol (4630-06-2,1569-60-4) + 2-methoxymethylsulfanyl-benzaldehyde (850306-53-5) → 3,10,10-trimethyl-2,3,10,10a-tetrahydro-1H,4aH-4-oxa-9-thia-phenanthrene + (2R,3S,6R)-3-Isopropenyl-2-(2-methoxymethylsulfanyl-phenyl)-6-methyl-tetrahydro-pyran

Guidance literature:

With toluene-4-sulfonic acid; trimethyl orthoformate; at 25 ℃; for 13h; Further Variations:; Reagents; Temperatures; Solvents; time; Product distribution;

DOI:10.1055/s-2005-862379

upstream raw materials:

formaldehyd

1-bromo-2-<(methoxymethyl)thio>benzene

Downstream raw materials:

1-dimethoxymethyl-2-methoxymethylsulfanyl-benzene