S-Hydroprene

Base Information

Chemical Name:S-Hydroprene
CAS No.:65733-18-8
Molecular Formula:C17H30O2
Molecular Weight:266.4189
Hs Code.:29161900
European Community (EC) Number:634-692-6
UNII:ZPY1YX719Z
ChEMBL ID:CHEMBL3184228
DSSTox Substance ID:DTXSID6035784
Metabolomics Workbench ID:54492
Nikkaji Number:J911.446G
Wikidata:Q27114784

Synonyms:S-Hydroprene;65733-18-8;(7S)-Hydroprene;Hydroprene (S)-form;(S)-hydroprene;ethyl (2E,4E,7S)-3,7,11-trimethyldodeca-2,4-dienoate;Ethyl (2E,4E,7S)-trimethyl-2,4-dodecadienoate;ZPY1YX719Z;DTXSID6035784;CHEBI:32110;2,4-Dodecadienoic acid, 3,7,11-trimethyl-, ethyl ester, (2E,4E,7S)-;S-Hydroprene (JAN);2,4-Dodecadienoic acid, 3,7,11-trimethyl-, ethyl ester, (S-(E,E))-;S-HYDROPRENE [JAN];DTXCID4015784;Ethyl 3,7,11-trimethyl-2,4-dodecadienoate;Zoecon RF-316;CAS-65733-18-8;UNII-ZPY1YX719Z;EPA Pesticide Chemical Code 128966;NCGC00160417-02;S-Hydroprene (>90%);HYDROPRENE, (S)-;HYDROPRENE, (+)-;(S)-(+)-HYDROPRENE;SCHEMBL8851930;CHEMBL3184228;HSDB 8317;HYDROPRENE (S)-FORM [MI];Tox21_111800;Tox21_301066;AKOS024307562;ZR-2006;NCGC00248275-01;NCGC00254968-01;NS00121511;D01814;S-Hydroprene, PESTANAL(R), analytical standard;Q27114784;(S,2E,4E)-Ethyl 3,7,11-trimethyldodeca-2,4-dienoate

Suppliers and Price of S-Hydroprene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
S-Hydroprene(>90%)
100mg
$ 340.00

Sigma-Aldrich
S-Hydroprene PESTANAL
250mg
$ 140.00

American Custom Chemicals Corporation
(S)-HYDROPRENE 95.00%
5MG
$ 505.82

Total 21 raw suppliers

Chemical Property of S-Hydroprene

Chemical Property:

Vapor Pressure:9.36E-05mmHg at 25°C
Refractive Index:1.461
Boiling Point:339.2 °C at 760 mmHg
Flash Point:153.8 °C
PSA：26.30000
Density:0.886 g/cm³
LogP:4.90450
XLogP3:6.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:10
Exact Mass:266.224580195
Heavy Atom Count:19
Complexity:300

Purity/Quality:

98%Min ^*data from raw suppliers

S-Hydroprene(>90%) ^*data from reagent suppliers

Safty Information:

Pictogram(s): N
Hazard Codes:N
Statements: 50/53
Safety Statements: 60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CCOC(=O)C=C(C)C=CCC(C)CCCC(C)C
Isomeric SMILES:CCOC(=O)/C=C(\C)/C=C/C[C@@H](C)CCCC(C)C
Uses Insect growth regulator; insecticide.

Technology Process of S-Hydroprene

There total 22 articles about S-Hydroprene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: (2E,4E)-3,7,11-trimethyl-2,4-dodecadienoic acid

: 1609-47-8
diethyl dicarbonate

: 36557-30-9,41096-46-2,41096-47-3,41205-09-8,53042-55-0,53042-72-1,53042-73-2,53833-71-9,57378-83-3,57378-84-4,65733-19-9,65733-18-8
(S)-hydroprene

Guidance literature:: With dmap; In toluene; at 15 - 25 ℃; for 2h; Reagent/catalyst; Solvent; Temperature; Green chemistry;

Reference yield: 79.0%

: 1356399-81-9
C₁₁H₂₃BO₂

: 122135-84-6,137273-43-9,122135-96-0
ethyl (E)-3-(trifluoromethylsulfonyloxy)but-2-enoate

: 36557-30-9,41096-46-2,41096-47-3,41205-09-8,53042-55-0,53042-72-1,53042-73-2,53833-71-9,57378-83-3,57378-84-4,65733-19-9,65733-18-8
(S)-hydroprene

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In 1,4-dioxane; water; at 80 ℃; for 20h; Inert atmosphere;
DOI:10.1016/j.tetlet.2012.02.019

Reference yield:

: 106-22-9
Citronellol

: 36557-30-9,41096-46-2,41096-47-3,41205-09-8,53042-55-0,53042-72-1,53042-73-2,53833-71-9,57378-83-3,57378-84-4,65733-19-9,65733-18-8
(S)-hydroprene

Guidance literature:: Multi-step reaction with 5 steps

1: 93 percent / H₂ / Pd/C / methanol / 50 h / 20 °C

2: PCC / CH₂Cl₂ / 2 h / 20 °C

3: 82 percent / diethyl ether / 15 h / 20 °C

4: 1.) O₃, O₂, 2.) Me₂S, 3.) Na₂SO₄, TsOH*H₂O / 1.) CH₂Cl₂, MeOH, -65 deg C, 2.) -60 deg C, 1h; -15 deg C, 1 h; 0 deg C, 1 h; 20 deg C, 12 h, 3.) benzene, reflux, 1 h

5: 2.) 10percent H₂SO₄ / 1.) ether, -10 deg C, 3 h, 2.) 1h

With dimethylsulfide; sulfuric acid; hydrogen; oxygen; toluene-4-sulfonic acid; ozone; sodium sulfate; pyridinium chlorochromate; palladium on activated charcoal; In methanol; diethyl ether; dichloromethane;
DOI:10.1007/BF00699985