Chlorine superoxide

Base Information

• Chemical Name: Chlorine superoxide
• CAS No.: 17376-09-9
• Molecular Formula: ClO2
• Molecular Weight: 67.4518
• Mol file: 17376-09-9.mol

Synonyms:chlorine superoxide;ClOO;OClO;ClOO(.);chloridodioxygen(O--O)(.);(ClOO)(.);CHEBI:29414;17376-09-9

Chemical Property of Chlorine superoxide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: g/cm³
• LogP: 0.50230
• XLogP3: 0.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 66.9586819
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [O]OCl

Technology Process of Chlorine superoxide

There total 4 articles about Chlorine superoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 2.0%

chlorine dioxide (10049-04-4,25052-55-5) → chlorine dioxide (17376-09-9) + clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2) + chlorine monoxide (14989-30-1)

Guidance literature:

Irradiation (UV/VIS);

DOI:10.1021/ja002148o

Reference yield:

ozone (153851-84-4) + clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2) → chlorine dioxide (17376-09-9) + chlorine dioxide (10049-04-4,25052-55-5)

Guidance literature:

gas-phase, low-pressure (< 1 torr) reaction between Cl and O3 with several ratios; trapping the products in an Ar matrix at 10 K and characterizing by IR and Raman spectra; Kinetics;

DOI:10.1021/j150614a021

Reference yield:

nitrate radical (12033-49-7,807306-99-6) + chlorine monoxide (14989-30-1) → chlorine dioxide (17376-09-9) + Nitrogen dioxide (10102-44-0)

Guidance literature:

In gaseous matrix; reaction of in situ generated ClO moleculs (by photolysis) with in situgenerated NO3 radical (N2 diluent, atmospheric pressure, 296 K, static conditions); monitoring by UV spectroscopy; Kinetics;

DOI:10.1016/0009-2614(84)87054-2

upstream raw materials:

chlorine dioxide

nitrate radical

chlorine monoxide

ozone

Downstream raw materials:

hypochlorous anhydride

chlorine monoxide