Tetraethylammonium perchlorate

Base Information

• Chemical Name: Tetraethylammonium perchlorate
• CAS No.: 2567-83-1
• Molecular Formula: C8H20N^.ClO4
• Molecular Weight: 229.704
• Hs Code.: 29239000
• European Community (EC) Number: 219-904-3
• NSC Number: 220061
• UN Number: 1479
• UNII: J5M9ZNC3QA
• DSSTox Substance ID: DTXSID10883866
• Mol file: 2567-83-1.mol

Synonyms:Tetraethylammonium perchlorate;2567-83-1;Ethanaminium, N,N,N-triethyl-, perchlorate;Ammonium, tetraethyl-, perchlorate;tetraethylazanium;perchlorate;Ethanaminium, N,N,N-triethyl-, perchlorate (1:1);EINECS 219-904-3;NSC 220061;Tetraethylammonium perchlorate (dry);NSC-220061;Tetraethylammonium perchlorate (dry) [Forbidden];TETRAETHYLAMMONIUMPERCHLORATE;tetraethylazanium perchlorate;tetraethylazanium,perchlorate;Tetraethyl ammonium perchlorate;Et4N+ClO4-;J5M9ZNC3QA;C8H20N.ClO4;SCHEMBL159225;C8-H20-N.Cl-O4;DTXSID10883866;WGHUNMFFLAMBJD-UHFFFAOYSA-M;CAA56783;MFCD00041977;NSC220061;AKOS015907948;AKOS032963899;N,N,N-Triethylethanaminium perchlorate;HY-W127676;Ethanaminium,N,N-triethyl-, perchlorate;AS-75475;CS-0185875;FT-0653004;T0839;D95387;A817969

Chemical Property of Tetraethylammonium perchlorate

Chemical Property:

• Appearance/Colour: White crystalline solid.
• Melting Point: >300 °C
• PSA: 74.27000
• LogP: 2.09710
• Water Solubility.: Soluble in water, acetone, acetonitrile and dimethyl sulfoxide.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 229.1080858
• Heavy Atom Count: 14
• Complexity: 143
• Transport DOT Label: Oxidizer

Purity/Quality:

98%,99%, ^*data from raw suppliers

TETRAETHYLAMMPERCHLORATE ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,O
• Hazard Codes: Xi-O,Xi,O
• Statements: 8-5-44-36/37/38
• Safety Statements: 47-37/39-26-17-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Perchlorates
• Canonical SMILES: CC[N+](CC)(CC)CC.[O-]Cl(=O)(=O)=O
• Uses: Tetraethylammonium perchlorate is used as supporting electrolyte in polarographic measurements.

Technology Process of Tetraethylammonium perchlorate

There total 6 articles about Tetraethylammonium perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

{copper(II)(bzthpy)(H2O)}diperchlorate + tetraethylammonium chloride (56-34-8) → chloro-{copper(II)(bzthpy)}perchlorate (121227-69-8) + tetraethylammonium perchlorate (2567-83-1)

Guidance literature:

In acetonitrile; Addn. of (Et4N)Cl soln. to soln. of Cu-complex.;

DOI:10.1002/hlca.19890720218

Reference yield: 73.0%

{copper(II)(bzoxpy)(H2O)}diperchlorate*MeCN + tetraethylammonium chloride (56-34-8) → chloro-{copper(II)(bzoxpy)}perchlorate (121227-67-6) + tetraethylammonium perchlorate (2567-83-1)

Guidance literature:

In acetonitrile; Addn. of (Et4N)Cl soln. to soln. of Cu-complex.;

DOI:10.1002/hlca.19890720218

Reference yield: 73.0%

tetraethylammonium chloride (56-34-8) + 2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl)pyridine (112362-30-8) → {chloro-copper(II)(mbzimpy)}perchlorate*H2O (121227-66-5) + tetraethylammonium perchlorate (2567-83-1)

Guidance literature:

In N,N-dimethyl-formamide; Addn. of Et4NCl soln. to soln. of ligand.; Addn. of Et2O to precipitate the complex, filtn., washing (CH2Cl2), recrystn. (DMF/Et2O).;

DOI:10.1002/hlca.19890720218

upstream raw materials:

3-diethylamino-5-phenyl-1,2,4-dithiazolium perchlorate

tetraethylammonium chloride

2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl)pyridine

tetraethylammonium bromide

Downstream raw materials:

methyl-phenyl-thioether

{Os₆(CO)18(CuNCCH₃)2}

Refernces

• 1、 Shee, Nirmal K.,Drew, Michael G. B.,Datta, Dipankar. "Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR". . p. 452 - 456. Retrieved 2017.
• 2、 Goga, Sergey T.,Lebed, Alexander V.,McHedlov-Petrossyan, Nikolay O.. "Conductivity and dissociation constants of quaternary ammonium perchlorates and picrates in 4-methyl-pentan-2-one". body text. p. 1887 - 1892. Retrieved 2011/07/30.