Triethylammonium

Base Information

• Chemical Name: Triethylammonium
• CAS No.: 17440-81-2
• Molecular Formula: C6H15 N . H
• Molecular Weight: 102.2
• Hs Code.: 2923900090
• DSSTox Substance ID: DTXSID50938506
• Nikkaji Number: J1.490.098E,J136.425A
• Wikidata: Q27120628
• Mol file: 17440-81-2.mol

Synonyms:TEAH;triethylammonium cation

Chemical Property of Triethylammonium

Chemical Property:

• Boiling Point: 90.5°Cat760mmHg
• Flash Point: °C
• PSA: 4.44000
• Density: g/cm³
• LogP: -0.06900
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 102.128274515
• Heavy Atom Count: 7
• Complexity: 25.7

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[NH+](CC)CC

Technology Process of Triethylammonium

There total 15 articles about Triethylammonium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

vanadium nitrene monocation (115858-94-1) → vanadium mononitride (24646-85-3) + triethylammonium (17440-81-2)

Guidance literature:

With triethylamine; In neat (no solvent, gas phase); proton transfer reaction;; mass spectrometry;;

DOI:10.1021/ja00228a002

Reference yield:

N-butylammonium cation (16999-97-6) + triethylamine (121-44-8) → triethylammonium (17440-81-2) + N-butylamine (109-73-9,85404-21-3)

Guidance literature:

at 128.84 ℃; Kinetics;

DOI:10.1021/ja012591e

Reference yield:

triphenylphosphinegold(I) cation (67215-69-4) + Pt(H)(P(C6H5)3)(AuP(C6H5)3)7(2+)={Pt(H)(P(C6H5)3)(AuP(C6H5)3)7}(2+) → bis(triphenylphosphine)gold(I)(1+) (47807-21-6) + Pt(Au(PPh3))8(2+) + triethylammonium (17440-81-2)

Guidance literature:

With triethyl amine; In not given;

upstream raw materials:

p-nitrophenol-triethylamine complex (proton-transfer complex)

4-(3-nitrophenylazo)-salicylate ion

triethylamine

2,6-di-tert-butyl-4-(3,5-di-tert-butyl-4-hydroxy-benzylidene)-cyclohexa-2,5-dienone

Downstream raw materials:

tri(n-propyl)amine-H⁺

triethylamine

hydrogen

chloride

Refernces

NUCLEOSIDE PHOSPHONODITHIOATES AS INTERMEDIATES IN THE PREPARATION OF DINUCLEOSIDE PHOSPHORODITHIOATES AND PHOSPHOROTHIOATES

10.1016/S0040-4039(01)80782-6

The research focuses on the synthesis of dinucleoside phosphorodithioates and phosphorothioates, which are analogues of oligonucleotides with potential applications as antiviral agents and in studies involving interactions with nucleic acids and proteins. The purpose of the study is to develop an alternative and convenient approach to synthesizing these analogues using protected nucleoside 3'-phosphonodithioates as starting materials. The researchers successfully converted 5'-O-(9-phenylxanthen-9-yl)thymidine into its 3'-phosphonodithioate derivative and further into dinucleoside phosphonothioate and dinucleoside phosphorodithioate with good overall yields. Key chemicals used in the process include triethylammonium salt, 3'-O-acetylthymidine, pivaloyl chloride, and sulfur. The study concludes that the procedure is potentially applicable to the synthesis of phosphorodithioate analogues of oligodeoxyribo- and oligoribo-nucleotides, both in solution and on solid supports, and that the synthesized dinucleoside phosphorodithioate (6a) is resistant to digestion by snake venom phosphodiesterase, bovine spleen phosphodiesterase, and nuclease PI.