5,10-Dihydro-5,10-dimethylphenazine

Base Information

• Chemical Name: 5,10-Dihydro-5,10-dimethylphenazine
• CAS No.: 15546-75-5
• Molecular Formula: C14H14N2
• Molecular Weight: 210.279
• Hs Code.: 29339900
• European Community (EC) Number: 605-010-4
• NSC Number: 149969
• DSSTox Substance ID: DTXSID30302286
• Nikkaji Number: J874.077A
• Wikidata: Q72469775
• Mol file: 15546-75-5.mol

Synonyms:15546-75-5;5,10-Dihydro-5,10-dimethylphenazine;5,10-dimethyl-5,10-dihydrophenazine;5,10-dimethylphenazine;NSC149969;5,10-Dimethylphenazin;N,N'-dimethyl phenazine;CN1c2ccccc2N(C)c3ccccc13;SCHEMBL482716;DTXSID30302286;MFCD00092904;5,10-dihydro-5,10-dimethlphenazine;5,10-dimethyl-5,10-dihydrophenazin;AKOS015850712;CS-W015103;NSC 149969;NSC-149969;5,10-dimethyl-5,10-dihydro-phenazine;AC-24979;BS-15492;D3392;FT-0657788;5,10-Dihydro-5,10-dimethylphenazine, 97%;A809645;J-009198;J-516460

Chemical Property of 5,10-Dihydro-5,10-dimethylphenazine

Chemical Property:

• Appearance/Colour: Yellowish crystal
• Vapor Pressure: 9.2E-05mmHg at 25°C
• Melting Point: 150-152 °C (dec.)(lit.)
• Refractive Index: 1.615
• Boiling Point: 339.426 °C at 760 mmHg
• PKA: 3.82±0.20(Predicted)
• Flash Point: 149.748 °C
• PSA: 9.86000
• Density: 1.117 g/cm³
• LogP: 3.23220
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: soluble in Toluene
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 210.115698455
• Heavy Atom Count: 16
• Complexity: 203

Purity/Quality:

99% ^*data from raw suppliers

5,10-Dihydro-5,10-dimethylphenazine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25-36/37/38
• Safety Statements: 26-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CN1C2=CC=CC=C2N(C3=CC=CC=C31)C

Technology Process of 5,10-Dihydro-5,10-dimethylphenazine

There total 14 articles about 5,10-Dihydro-5,10-dimethylphenazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,10-dihydrophenazine (613-32-1) + methyl iodide (74-88-4) → 5,10-dihydro-5,10-dimethylphenazine (15546-75-5)

Guidance literature:

With n-butyllithium; In 1,2-dimethoxyethane; hexane; for 0.833333h; Ambient temperature;

Reference yield:

methyl iodide (74-88-4) → 5,10-dihydro-5,10-dimethylphenazine (15546-75-5)

Guidance literature:

With 1,2-dimethoxyethane;

DOI:10.1021/ja01580a019

Reference yield:

methyl iodide (74-88-4) → 5,10-dihydro-5,10-dimethylphenazine (15546-75-5)

Guidance literature:

With 1,2-dimethoxyethane;

DOI:10.1021/ja01580a019

upstream raw materials:

N,N-dimethyl-1,2-phenylenediamine

cyclohexane-1,2-dione

Phenazin

methyl iodide

Downstream raw materials:

3C₁₄H₁₄N₂*2C₁₂H₈N₂*5C₁₂H₄N₄

5,10-Dimethyl-5,10-dihydro-phenazine; compound with 1,3-dinitro-benzene

5,10-Dimethyl-5,10-dihydro-phenazine; compound with 1,4-dinitro-benzene

5,10-Dimethyl-5,10-dihydro-phenazine; compound with 1,3,5-trinitro-benzene

Refernces

• 1、 Dietz, K.,Keller, H. J.,Noethe, D.,Wehe, D.. "Charge Transfer and Addition Products between Alkylated Phenazine Donors and Ethanetetracarbonitrile (TCNE): Crystal and Molecular Structure of the Dye 2,2'-(2,3,5,10-Tetrahydro-5,10-dimethylphenazine-2,3-ylidene)bis(propanedinitrile) (TMPP)". . p. 7581 - 7585. Retrieved 1982.
• 2、 Sugimoto, Akira,Kotani, Takeshi,Tsujimoto, Junko,Yoneda, Shigeo. "Preparation and Properties of Electron Donor Acceptor Complexes of the Compounds having Capto-dative Substituents". . p. 435 - 438. Retrieved 2007/10/02.