5,10-Dihydro-5,10-dimethylphenazine

Base Information

• Chemical Name: 5,10-Dihydro-5,10-dimethylphenazine
• CAS No.: 15546-75-5
• Molecular Formula: C14H14N2
• Molecular Weight: 210.279
• Hs Code.: 29339900
• European Community (EC) Number: 605-010-4
• NSC Number: 149969
• DSSTox Substance ID: DTXSID30302286
• Nikkaji Number: J874.077A
• Wikidata: Q72469775
• Mol file: 15546-75-5.mol

Synonyms:15546-75-5;5,10-Dihydro-5,10-dimethylphenazine;5,10-dimethyl-5,10-dihydrophenazine;5,10-dimethylphenazine;NSC149969;5,10-Dimethylphenazin;N,N'-dimethyl phenazine;CN1c2ccccc2N(C)c3ccccc13;SCHEMBL482716;DTXSID30302286;MFCD00092904;5,10-dihydro-5,10-dimethlphenazine;5,10-dimethyl-5,10-dihydrophenazin;AKOS015850712;CS-W015103;NSC 149969;NSC-149969;5,10-dimethyl-5,10-dihydro-phenazine;AC-24979;BS-15492;D3392;FT-0657788;5,10-Dihydro-5,10-dimethylphenazine, 97%;A809645;J-009198;J-516460

Chemical Property of 5,10-Dihydro-5,10-dimethylphenazine

Chemical Property:

• Appearance/Colour: Yellowish crystal
• Vapor Pressure: 9.2E-05mmHg at 25°C
• Melting Point: 150-152 °C (dec.)(lit.)
• Refractive Index: 1.615
• Boiling Point: 339.426 °C at 760 mmHg
• PKA: 3.82±0.20(Predicted)
• Flash Point: 149.748 °C
• PSA: 9.86000
• Density: 1.117 g/cm³
• LogP: 3.23220
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: soluble in Toluene
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 210.115698455
• Heavy Atom Count: 16
• Complexity: 203

Purity/Quality:

99% ^*data from raw suppliers

5,10-Dihydro-5,10-dimethylphenazine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25-36/37/38
• Safety Statements: 26-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CN1C2=CC=CC=C2N(C3=CC=CC=C31)C

Technology Process of 5,10-Dihydro-5,10-dimethylphenazine

There total 14 articles about 5,10-Dihydro-5,10-dimethylphenazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,10-dihydrophenazine (613-32-1) + methyl iodide (74-88-4) → 5,10-dihydro-5,10-dimethylphenazine (15546-75-5)

Guidance literature:

With n-butyllithium; In 1,2-dimethoxyethane; hexane; for 0.833333h; Ambient temperature;

Reference yield:

methyl iodide (74-88-4) → 5,10-dihydro-5,10-dimethylphenazine (15546-75-5)

Guidance literature:

With 1,2-dimethoxyethane;

DOI:10.1021/ja01580a019

Reference yield:

methyl iodide (74-88-4) → 5,10-dihydro-5,10-dimethylphenazine (15546-75-5)

Guidance literature:

With 1,2-dimethoxyethane;

DOI:10.1021/ja01580a019

upstream raw materials:

N,N-dimethyl-1,2-phenylenediamine

cyclohexane-1,2-dione

Phenazin

methyl iodide

Downstream raw materials:

3C₁₄H₁₄N₂*2C₁₂H₈N₂*5C₁₂H₄N₄

5,10-Dimethyl-5,10-dihydro-phenazine; compound with 1,3-dinitro-benzene

5,10-Dimethyl-5,10-dihydro-phenazine; compound with 1,4-dinitro-benzene

5,10-Dimethyl-5,10-dihydro-phenazine; compound with 1,3,5-trinitro-benzene

Refernces

Multi-electron redox phenazine for ready-to-charge organic batteries

10.1039/c7gc00849j

The research investigates the use of N,N'-substituted phenazine (NSPZ) derivatives as a new class of p-type organic redox centers for building ready-to-charge organic batteries. The study demonstrates that NSPZ cathodes can facilitate reversible two-electron transfer at 3.7 and 3.1 V in dual-ion batteries, resulting in a specific energy of 622 Wh kg^-1. The chemicals that played a significant role in this research include 5,10-dihydro-5,10-dimethyl phenazine (DMPZ), mP-DPPZ, and pP-DPPZ, which were synthesized and used as active materials in the battery electrodes. Various electrolytes, such as LiClO4, LiTFSI, LiPF6, NaClO4, and MgClO4, were employed to test the electrolyte salt and solvent dependence of the anion association reaction. The research also involved the use of conductive carbon (Super P) and polytetrafluoroethylene (PTFE) binder for electrode fabrication, as well as tetraethylene glycol dimethyl ether (TEGDME) as a solvent for the electrolyte.

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