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15546-75-5

Basic Information
CAS No.: 15546-75-5
Name: 5,10-Dimethyldihydrophenazine
Article Data: 13
Molecular Structure:
Molecular Structure of 15546-75-5 (5,10-Dimethyldihydrophenazine)
Formula: C14H14N2
Molecular Weight: 210.279
Synonyms: 5,10-Dihydro-5,10-dimethylphenazine;5,10-Dimethyl-5,10-dihydrophenazine;N,N'-Dimethylphenazine;NSC 149969;
Density: 1.117 g/cm3
Melting Point: 150-152 °C (dec.)(lit.)
Boiling Point: 339.426 °C at 760 mmHg
Flash Point: 149.748 °C
Appearance: Yellowish crystal
Hazard Symbols: ToxicT
Risk Codes: 23/24/25-36/37/38
Safety: 26-28-36/37/39-45
Transport Information: UN 2811 6.1/PG 3
PSA: 9.86000
LogP: 3.23220
Synthetic route

5,10-dimethyl-2,3,5,10-tetrahydro-phenazine

15546-75-5

5,10-dihydro-5,10-dimethylphenazine

Conditions
ConditionsYield
Lufteinwirkung;
2836-03-5

N,N-dimethyl-1,2-phenylenediamine

765-87-7

cyclohexane-1,2-dione

15546-75-5

5,10-dihydro-5,10-dimethylphenazine

Conditions
ConditionsYield
With sodium acetate; acetic acid
92-82-0

Phenazin

74-88-4

methyl iodide

15546-75-5

5,10-dihydro-5,10-dimethylphenazine

Conditions
ConditionsYield
With potassium
613-32-1

5,10-dihydrophenazine

74-88-4

methyl iodide

15546-75-5

5,10-dihydro-5,10-dimethylphenazine

Conditions
ConditionsYield
With n-butyllithium In 1,2-dimethoxyethane; hexane for 0.833333h; Ambient temperature;2.1 g
Stage #1: 5,10-dihydrophenazine With sodium In tetrahydrofuran; toluene at 20℃; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran; toluene Inert atmosphere;
5-methyl-phenazinium-methyl sulfate

5-methyl-phenazinium-methyl sulfate

15546-75-5

5,10-dihydro-5,10-dimethylphenazine

Conditions
ConditionsYield
With methyl magnesium iodide; diethyl ether
74-88-4

methyl iodide

dilithium-compound of 5,10-dihydro-phenazine

dilithium-compound of 5,10-dihydro-phenazine

15546-75-5

5,10-dihydro-5,10-dimethylphenazine

Conditions
ConditionsYield
With 1,2-dimethoxyethane
74-88-4

methyl iodide

disodium-compound of 5,10-dihydro-phenazine

disodium-compound of 5,10-dihydro-phenazine

15546-75-5

5,10-dihydro-5,10-dimethylphenazine

Conditions
ConditionsYield
With 1,2-dimethoxyethane
74-88-4

methyl iodide

lithium-compound of 5-methyl-5,10-dihydro-phenazine

lithium-compound of 5-methyl-5,10-dihydro-phenazine

15546-75-5

5,10-dihydro-5,10-dimethylphenazine

5-methyl-phenazinium-methyl sulfate

5-methyl-phenazinium-methyl sulfate

A

20057-16-3

fully reduced 5-methylphenazinium

B

15546-75-5

5,10-dihydro-5,10-dimethylphenazine

Conditions
ConditionsYield
With methyl magnesium iodide; diethyl ether anschliessend Behandeln mit H2O;
765-87-7

cyclohexane-1,2-dione

15546-75-5

5,10-dihydro-5,10-dimethylphenazine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous HCl
2: Lufteinwirkung
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Chemistry

Molecular Structure of 5,10-Dimethyldihydrophenazine (CAS NO.15546-75-5):

IUPAC Name: 5,10-dimethylphenazine
Empirical Formula: C14H14N2
Molecular Weight: 210.2744
H bond acceptors: 2
H bond donors: 0
Freely Rotating Bonds: 0
Polar Surface Area: 6.48 Å2
Index of Refraction: 1.615
Molar Refractivity: 65.73 cm3
Molar Volume: 188.1 cm3
Surface Tension: 41.3 dyne/cm
Density: 1.117 g/cm3
Flash Point: 149.7 °C
Enthalpy of Vaporization: 58.29 kJ/mol
Boiling Point: 339.4 °C at 760 mmHg
Vapour Pressure: 9.2E-05 mmHg at 25°C
Melting point: 150-152 °C (dec.)(lit.)
Product Categories: Heterocyclic Building Blocks; N-Containing;Others

Safety Profile

Hazard Codes: ToxicT
Risk Statements: 23/24/25-36/37/38
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-28-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
HazardClass: 6.1(b)
PackingGroup: III

Specification

  5,10-Dimethyldihydrophenazine , with CAS number of 15546-75-5, can be called phenazine, 5,10-dihydro-5,10-dimethyl- ; 5,10-Dihydro-5,10-dimethylphenazine ; 5,10-dihydro-5,10-dimethylphenazine 98% .