Dimethyl(oct-1-EN-2-YL)phenylsilane

Base Information

• Chemical Name: Dimethyl(oct-1-EN-2-YL)phenylsilane
• CAS No.: 87437-03-4
• Molecular Formula: C16H26Si
• Molecular Weight: 246.468
• DSSTox Substance ID: DTXSID60579505
• Nikkaji Number: J370.877B
• Wikidata: Q82470037
• Mol file: 87437-03-4.mol

Synonyms:DIMETHYL(OCT-1-EN-2-YL)PHENYLSILANE;87437-03-4;DTXSID60579505

Chemical Property of Dimethyl(oct-1-EN-2-YL)phenylsilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 246.180377364
• Heavy Atom Count: 17
• Complexity: 224

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCCCCC(=C)[Si](C)(C)C1=CC=CC=C1

Technology Process of Dimethyl(oct-1-EN-2-YL)phenylsilane

There total 15 articles about Dimethyl(oct-1-EN-2-YL)phenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

n-octyne (629-05-0) + dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane (185990-03-8) → dimethyl(oct-1-en-2-yl)(phenyl)silane (87437-03-4)

Guidance literature:

dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane; With copper(l) chloride; johnphos; sodium t-butanolate; In tetrahydrofuran; at 0 ℃; for 0.5h; Inert atmosphere;

n-octyne; In tetrahydrofuran; methanol; at 0 ℃; for 24h; regioselective reaction; Inert atmosphere;

DOI:10.1021/ja109464u

Reference yield: 74.0%

C9H14MgSi (87436-97-3) + oct-1-en-2-yl diphenyl phosphate (87436-98-4) → dimethyl(oct-1-en-2-yl)(phenyl)silane (87437-03-4)

Guidance literature:

With tris-(o-tolyl)phosphine; palladium diacetate; In hexane; at 25 ℃; for 0.5h;

DOI:10.1016/S0040-4039(00)81831-6

Reference yield: 74.0%

C25H36MgMnSi3 + oct-1-en-2-yl diphenyl phosphate (87436-98-4) → dimethyl(oct-1-en-2-yl)(phenyl)silane (87437-03-4)

Guidance literature:

In tetrahydrofuran; diethyl ether; at 25 ℃; for 5h;

DOI:10.1016/S0040-4039(00)84475-5

upstream raw materials:

n-octyne

dimethyl(phenyl)silyllithium

oct-1-en-2-yl diphenyl phosphate

C₉H₁₄MgSi